Waste water zero-discharge acetylene production technology

A production process and zero-emission technology, applied in acetylene generators, parts of acetylene gas generators, petroleum industry, etc., can solve problems such as incomplete reaction between calcium carbide and water, and achieve favorable management and control, and stable process parameters , The effect of reasonable and safe process design

Inactive Publication Date: 2016-01-27
QINGDAO UNIV OF SCI & TECH +2
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] The calcium carbide slurry from the acetylene generator not only contains dissolved acetylene, but more importantly, it contains a lot of undecomposed tiny calc...

Method used

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  • Waste water zero-discharge acetylene production technology
  • Waste water zero-discharge acetylene production technology
  • Waste water zero-discharge acetylene production technology

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Embodiment 1

[0027] Such as figure 2 As shown, after the water from the clear liquid pool passes through the heat exchanger to regulate the temperature, it is fed into the acetylene generator at the same time as calcium carbide at a predetermined flow rate, and the pressure and temperature of the generator are kept at the set values. The calcium carbide and water in the generator generate reaction to generate acetylene gas and calcium carbide slurry; the acetylene gas is washed and compressed from the top of the generator in sequence, and then enters the acetylene cleaning station, and is removed with a fresh sodium solution with an available chlorine of 0.1% to 0.12% and a pH value of 7 to 8 In addition to impurities such as hydrogen sulfide and phosphine in acetylene gas, the sub-sodium wastewater enters the first desorption tower and is sprayed under negative pressure conditions. After removing acetylene gas, part of the sub-sodium wastewater goes to the sub-sodium compounding device, a...

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PUM

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Abstract

The invention relates to a wet method production technology for preparing acetylene from calcium carbide. Crude acetylene from a generator needs a large volume of sodium hypochlorite solution for cleaning, After the generated waste sodium hypochlorite solution goes through a first desorption tower and acetylene is recovered, part of the solution is used for compounding of a sodium hypochlorite solution, and part of the solution goes through a transition tank and goes into a concentration tank for reuse. Through adjusting of the compounding proportion, all the waste water generated in the technology can be reused without discharge. After a diluted calcium carbide slag slurry overflowed from the generator goes through a second desorption tower and acetylene is recovered, the diluted calcium carbide slag slurry goes into the concentration tank for concentration; the supernatant in the concentration tank is cooled in water cooling tower, a heat exchanger is added in front of an acetylene generator, circulating water cooling is carried out, stable water input temperature and water inflow of the acetylene generator are ensured, and the stability and the controllability of technology production are raised. The provided technology raises the acetylene yield, ensures water balance, achieves waste water zero discharge and has good economic and environmental protection benefits compared with traditional technologies.

Description

Technical field [0001] The present invention involves a wet process for the production of acetylene to produce acetylene. This process realizes the reclaiming process of sodium hypochlorite, so that the wastewater of the process is zero emissions. At the same timeAcetylene device in the production process of polyvinyl chloride. Background technique [0002] Acetylene production process is mainly divided into electrical and ethylene method, and the stone method is divided into dry and wet method.At present, it is commonly used in the country to produce acetracks and wetting techniques.As we all know, the reaction of the electric stones and the water will generate acetylene and release a lot of heat. The reaction equation is shown in the following formula. [0003] CAC 2 +2H 2 O → C 2 H 2 +CA (OH) 2 +129.8kj / mol [0004] Because electrical stones often contain a small amount of impurities such as sulfide, phosphide, and the generated acetylene gas, which contains a small amount of ...

Claims

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Application Information

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IPC IPC(8): C10H21/00
Inventor 杨霞李玉刚罗代晏郑世清钟杰水卢主枫
Owner QINGDAO UNIV OF SCI & TECH
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