Waste utilization based environment friendly phosphate fertilizer, preparation method and application thereof
An environmentally friendly, phosphate fertilizer technology, applied in the directions of phosphate fertilizer, application, Thomas phosphate fertilizer, etc., can solve the problems of increasing the available phosphorus content of plants, insufficient activation effect, heavy metal pollution, etc. effect of demand
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Embodiment 1
[0027] An environment-friendly phosphate fertilizer based on waste utilization of the present invention is mainly prepared by mixing liquid active silicon-rich substances and phosphorus-containing waste minerals, and activating phosphorus-containing waste minerals with liquid active silicon-rich substances.
[0028] Phosphorus-containing waste minerals in the present embodiment adopt phosphorus-containing slag from the phosphate industry (Calcium Silicate Company, the U.S., Tennessee), and respectively adopt monosilicic acid solution (Zumsil, TerraTech.Inc., U.S., Florida) , diatomite (Palkarramine, Australia, northern Queensland) as rich in active silicon material, wherein diatomite is as a contrast, specifically prepared according to the following steps:
[0029] a) preparing phosphorus-containing slag, grinding the phosphorus-containing slag to increase its specific surface area; controlling the particle size of the phosphorus-containing slag to 0.001-5mm;
[0030] b) fully...
Embodiment 2
[0047] This embodiment adopts phosphate waste (TPR) from the Republic of Tunisia, and the water-extracted state and the acid-extracted state of heavy metals Cd, Co, Cr, Pb, Hg and Ni in this phosphate waste have been determined (the The heavy metal content is shown in the following table 4), the water extraction state is extracted with deionized water, and the acid extraction state is extracted with 0.1MHCl and 2MHNO 3 Extraction, the water-extracted state is the soluble part, and the corresponding acid-extracted state is the potentially mobile part. 2g of phosphate waste was added to 20ml of solution and mixed for 1h, then centrifuged at 6000g for 15min to get the supernatant, and the heavy metal content was determined by ICP-OES (PerkinElmer Optima5300DV).
[0048] Table 4. Mobile heavy metal content in phosphate waste (TPR) from the Republic of Tunisia
[0049]
[0050] Using a high-concentration monosilicic acid solution as a material rich in active silicon, a high-con...
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