Thermosetting composition, cured film, color filter, liquid crystal display element, solid-state imaging element, and light-emitting diode emitter
A technology of thermosetting and composition, applied in the direction of optical filter, optical element, nonlinear optics, etc., can solve the problem of insufficient flatness and heat resistance of polyester amic acid composition, insufficient heat resistance, and light resistance Insufficient performance and other problems, to achieve the effect of improved display quality and reliability, and high practicability
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[0155] Next, the present invention will be specifically described by way of synthesis examples, reference examples, examples, and comparative examples, but the present invention is not limited by these examples. First, the polyester amic acid solution (synthesis example 1, synthesis example 2, synthesis example 3, and synthesis example 4) containing the reaction product of tetracarboxylic dianhydride, diamine, and a polyvalent hydroxyl compound was synthesize|combined as follows.
Synthetic example 1
[0156] [Synthesis Example 1] Synthesis of Polyester Amic Acid Solution (A1)
[0157] In a four-necked flask equipped with a stirrer, dehydrated and purified methyl 3-methoxypropionate (hereinafter abbreviated as "MMP"), 3,3', 4,4'-bis Phenyl ether tetracarboxylic dianhydride (hereinafter abbreviated as "ODPA"), 1,4-butanediol, and benzyl alcohol were stirred at 130° C. for 3 hours under a stream of dry nitrogen.
[0158]
[0159] Thereafter, the reaction solution was cooled to 25°C, and 3,3'-diaminodiphenylsulfone (hereinafter abbreviated as "DDS") and MMP were added in the following weight, and stirred at 20°C to 30°C for 2 hours , stirring at 115° C. for 1 hour.
[0160] DDS 29.33g
[0161] MMP 183.04g
[0162] [Z / Y=3.0, (Y+Z) / X=0.8]
[0163] The solution was cooled to room temperature to obtain a light yellow transparent 30% by weight solution (A1) of polyester amic acid. A part of the solution was sampled, and the weight average molecular weight was measured by GPC...
Synthetic example 2
[0164] [Synthesis Example 2] Synthesis of Polyester Amic Acid Solution (A2)
[0165] In a four-necked flask with a stirrer, dehydrated and purified propylene glycol monomethyl ether acetate (hereinafter abbreviated as "PGMEA"), 1,2,3,4-butane tetra Carboxylic acid dianhydride (hereinafter abbreviated as "BT-100"), SMA1000P (trade name; styrene-maleic anhydride copolymer, Chuanyuan Chemical Co., Ltd.), 1,4-butanediol, benzyl alcohol, in Stirring was performed at 125° C. for 3 hours under a stream of dry nitrogen.
[0166]
[0167] Then, the reaction liquid was cooled to 25 degreeC, DDS and PGMEA were thrown in by the following weight, and after stirring at 20 degreeC - 30 degreeC for 2 hours, it stirred at 125 degreeC for 2 hours.
[0168] DDS 9.60g
[0169] PGMEA 36.00g
[0170] [Z / Y=2.7, (Y+Z) / X=0.9]
[0171] The solution was cooled to room temperature to obtain a light yellow transparent 30% by weight solution (A2) of polyester amic acid. A part of the solution was s...
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