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A method for preparing a silicon epitaxial layer on a heavily doped thin phosphorus substrate for a Schottky device

A silicon epitaxial layer and epitaxial layer technology, applied in chemical instruments and methods, semiconductor/solid-state device manufacturing, electrical components, etc., can solve different flow field distributions, increase the difficulty of thickness uniformity control, and increase the difficulty of epitaxial defect control. and other problems, to achieve the effect of good uniformity, improved performance and yield

Active Publication Date: 2018-01-12
CHINA ELECTRONICS TECH GRP NO 46 RES INST +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

But at the same time, due to the difference in the thickness of the substrate, the distribution of the flow field in the epitaxial cavity will inevitably be different, which increases the difficulty of thickness uniformity control
Moreover, substrates with different thicknesses need to experience different thermal stresses during the epitaxial growth process, which greatly increases the difficulty of controlling epitaxial defects.

Method used

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  • A method for preparing a silicon epitaxial layer on a heavily doped thin phosphorus substrate for a Schottky device
  • A method for preparing a silicon epitaxial layer on a heavily doped thin phosphorus substrate for a Schottky device
  • A method for preparing a silicon epitaxial layer on a heavily doped thin phosphorus substrate for a Schottky device

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] (1) Use hydrogen chloride with a purity ≥ 99.99% to polish the base of the epitaxial furnace at high temperature to completely remove the residual deposits on the base. The eclipse time was set to 5 min. Then wrap a layer of undoped polysilicon on the graphite base, the growth material is trichlorosilane gas with a purity ≥ 99.95%, the flow rate is set to 5 g / min, and the growth time is set to 5 min.

[0022] (2) Load a phosphorus-doped silicon substrate sheet with a thickness of 290±10 μm into the pit of the base of the epitaxial furnace, and then use nitrogen and hydrogen with a purity of ≥99.999% to purge the epitaxial furnace cavity for 8 minutes, and set the gas flow rate to 150 L / min.

[0023] (3) Use hydrogen chloride gas to perform in-situ polishing on the surface of the silicon substrate to remove the micro-damage layer and improve the surface lattice quality. Use hydrogen gas to transport hydrogen chloride gas into the reaction chamber. The hydrogen flow rat...

Embodiment 2

[0031] (1) Use hydrogen chloride with a purity ≥ 99.99% to polish the base of the epitaxial furnace at high temperature to completely remove the residual deposits on the base. The eclipse time was set to 5 min. Then wrap a layer of undoped polysilicon on the graphite base, the growth material is trichlorosilane gas with a purity ≥ 99.95%, the flow rate is set to 4 g / min, and the growth time is set to 4 min.

[0032] (2) Load a phosphorus-doped silicon substrate sheet with a thickness of 290±10 μm into the pit of the base of the epitaxial furnace, and use nitrogen and hydrogen with a purity of ≥99.999% to purge the epitaxial furnace cavity for 8 minutes in sequence, and set the gas flow rate to 150 L / min.

[0033] (3) Use hydrogen chloride gas to perform in-situ polishing on the surface of the silicon substrate to remove the micro-damage layer and improve the quality of the surface lattice. Use hydrogen gas to transport hydrogen chloride into the reaction chamber. The hydroge...

Embodiment 3

[0041] (1) Use hydrogen chloride with a purity ≥ 99.99% to polish the base of the epitaxial furnace at high temperature to completely remove the residual deposits on the base. The eclipse time was set to 5 min. Then wrap a layer of undoped polysilicon on the graphite base, the growth material is trichlorosilane gas with a purity ≥ 99.95%, the flow rate is set to 6 g / min, and the growth time is set to 6 min. In the subsequent mass transfer effect, the polysilicon on the base can encapsulate the back and side surfaces of the phosphorus substrate, suppressing the volatilization of substrate impurities.

[0042] (2) Load a phosphorus-doped silicon substrate sheet with a thickness of 290±10 μm into the pit of the base of the epitaxial furnace, and use nitrogen and hydrogen with a purity of ≥99.999% to purge the epitaxial furnace cavity for 10 minutes in sequence, and set the gas flow rate to 150 L / min.

[0043] (3) Use hydrogen chloride gas to perform in-situ polishing on the su...

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Abstract

The invention relates to a method for preparing a silicon epitaxial layer on a heavily doped thin phosphorus substrate for a Schottky device, which adopts an atmospheric pressure flat-plate epitaxial furnace. Polish the furnace base; (2) Load phosphorus-doped silicon substrates into the epitaxial furnace, and purge the epitaxial furnace cavity with nitrogen and hydrogen with purity ≥ 99.999% in sequence; (3) Use hydrogen chloride gas to polish the surface of the silicon substrate ; (4) Purging the surface of the silicon substrate with a large flow of hydrogen; (5) Growing the intrinsic epitaxial layer; (6) Purging the reaction chamber of the epitaxial furnace with variable flow; (7) Doping epitaxy layer growth. The beneficial effect is that the thickness non-uniformity of the epitaxial layer is less than 1%, the resistivity non-uniformity is less than 1%, the surface has no defects such as stacking faults, dislocations, slip lines, fog, etc., and the width of the transition zone can be less than 1 um under the best conditions , which fully meets the requirements of the Schottky device on the silicon epitaxial layer, and improves the performance and yield of the Schottky device.

Description

technical field [0001] The invention relates to a preparation technology of a silicon epitaxial layer for a Schottky device, in particular to a preparation method for a silicon epitaxial layer on a heavily doped thin phosphorus substrate for a Schottky device. Background technique [0002] Schottky devices are low-power, high-current, ultra-high-speed semiconductor devices. Key devices such as breakdown voltage and forward voltage drop basically depend on the parameters of the epitaxial layer substrate, especially high-performance silicon Schottky diodes. The quality of the epitaxial layer has higher requirements, such as better uniformity, narrow transition zone, and low defect density. At present, Schottky devices prefer the epitaxial layer on the heavily doped phosphorus substrate, which can greatly reduce the forward voltage drop and reduce the power consumption of the device. bottom (resistivity 0.002~0.004 Ώ cm), due to the higher doping concentration, the substrate i...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C30B25/02H01L21/02
Inventor 王文林高航李杨李明达
Owner CHINA ELECTRONICS TECH GRP NO 46 RES INST
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