Method for dispersing complex conducting agent in electrode slurry for lithium ion capacitor
A composite conductive agent and capacitor electrode technology, which is applied in the directions of hybrid capacitor electrodes, capacitors, electrolytic capacitors, etc., can solve problems such as the inability to effectively form a conductive network structure, and the conductive agent is not easily dispersed, and achieves low cost, improved conductivity, and dispersion effects. Good results
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Embodiment 1
[0024] (1) Weighing: Weigh each component according to the ratio of 0.5% graphene, 5.5% carbon nanotubes with a diameter of 50nm, and the balance of conductive carbon black with a particle size of 10nm. Among them, graphene, carbon nanotubes and Conductive carbon black constitutes a composite conductive agent, and simultaneously weigh N-methylpyrrolidone that is 4 times the quality of the composite conductive agent and a surfactant that is 5% of the composite conductive agent quality, and stand-by, wherein the surfactant is linolenic acid.
[0025] (2) Step-by-step feeding and dispersion: firstly mix conductive carbon black with N-methylpyrrolidone and surfactant, then ultrasonically disperse for 20min under the condition of frequency 15KHz and power 200W, and inject hydrogen into the feed liquid every 1min during ultrasonic dispersion , each time the hydrogen gas is injected for 5S, the amount of hydrogen injected is 0.3m 3 / h, followed by adding carbon nanotubes and carrying...
Embodiment 2
[0027] (1) Weighing: Weigh each component according to the ratio of 14.5% graphene, 14.5% carbon nanotubes with a diameter of 100nm, and the balance of conductive carbon black with a particle size of 50nm. Among them, graphene, carbon nanotubes and Conductive carbon black constitutes a composite conductive agent, and simultaneously takes by weighing N-methylpyrrolidone that is 9 times the quality of the composite conductive agent and a surfactant that is 15% of the composite conductive agent quality, stand-by, wherein the surfactant is hexadecyl Trimethylammonium bromide, stearic acid, and sodium lauryl sulfate are mixed in a mass ratio of 1:1:1.
[0028] (2) Step-by-step feeding and dispersion: firstly mix conductive carbon black with N-methylpyrrolidone and surfactant, then ultrasonically disperse for 30min under the condition of frequency 20KHz and power 300W, and inject hydrogen into the feed liquid every 3min during ultrasonic dispersion , each time the hydrogen gas is in...
Embodiment 3
[0030] (1) Weighing: Weigh each component according to the ratio of 10% graphene, 12% carbon nanotubes with a diameter of 60nm, and the balance of conductive carbon black with a particle size of 20nm. Among them, graphene, carbon nanotubes and conductive carbon black Carbon black constitutes a composite conductive agent, and simultaneously takes by weighing N-methylpyrrolidone that is 7 times the quality of the composite conductive agent and a surfactant that is 10% of the composite conductive agent quality, stand-by, wherein the surfactant is linolenic acid, cetyl One or more of alkyltrimethylammonium bromide, stearic acid, sodium lauryl sulfate, sodium dodecylbenzenesulfonate;
[0031] (2) Step-by-step feeding and dispersion: firstly mix the conductive carbon black with N-methylpyrrolidone and surfactant, then ultrasonically disperse for 25min under the condition of frequency 18KHz and power 250W, and inject hydrogen into the feed liquid every 2min during ultrasonic dispersio...
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