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Nano hydrophobic and oleophobic coating and preparation method of coating

A hydrophobic, oleophobic, and coating technology, applied in coatings and other directions, can solve the problems of uneven gel coating, small film thickness, and high equipment requirements, so as to improve drainage effect, reduce sliding angle, and increase contact corner effect

Inactive Publication Date: 2015-05-13
宁波华尔克应用材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among them, the chemical vapor deposition method has high requirements for equipment and high investment costs, resulting in high production costs; the sol-gel high-temperature sintering method may cause uneven gel coating in large-scale production, and the heat treatment process of gel preparation The control of medium parameters has too much influence on the properties of the gel; the magnetron sputtering method is not yet suitable for mass production, and the coating efficiency is low, and the film thickness is relatively small, which cannot reach the thickness required for photocatalysis
However, the hydrophobic angle of the film layer of hydrophobic glass gradually decreases with the passage of time, and the timeliness is poor. It cannot guarantee the self-cleaning effect of the glass product during its service life, so it cannot guarantee the true self-cleaning.

Method used

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  • Nano hydrophobic and oleophobic coating and preparation method of coating

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] Percentage by weight, ethanol 72%, isopropanol 6.9%, siloxane oligomer 20.1%, and the rest is the proportion of ethyl sulfate to obtain the solution after fully mixing. Wipe the glass surface to be treated with a non-woven cloth until the entire surface is completely wiped. After one minute, use the same non-woven cloth to wipe the surface in overlapping circles for one minute. Then use a clean non-woven cloth to wipe off the residual liquid on the glass surface, and then use microfiber cloth, cotton or paper towels to polish the surface of the material to complete the coating of the material surface film layer. After standing for a few minutes, it will be on the glass A nano-hydrophobic and oleophobic coating with a particle size of 30-50nm is formed on the surface. Perform a performance test and the results are as follows:

[0023] performance

[0024] Abrasion test: Use a one-pound stress abrasion head to treat the glass surface for 1600 cycles. The conta...

Embodiment 2

[0026] Percentage by weight, ethanol 73%, isopropanol 5.8%, siloxane oligomer 18.4%, and the rest is the proportion of ethyl sulfate to obtain the solution after fully mixing. Wipe the glass surface to be treated with a non-woven cloth until the entire surface is completely wiped. After one minute, use the same non-woven cloth to wipe the surface in overlapping circles for one minute. Then use a clean non-woven cloth to wipe off the residual liquid on the glass surface, and then use microfiber cloth, cotton or paper towels to polish the surface of the material to complete the coating of the material surface film layer. After standing for a few minutes, it will be on the glass A nano-hydrophobic and oleophobic coating with a particle size of 50-80nm is formed on the surface. Perform a performance test and the results are as follows:

[0027] performance

[0028] Abrasion test: Use a one-pound stress abrasion head to treat the glass surface for 1600 cycles. The conta...

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Abstract

The invention relates to a nano hydrophobic and oleophobic coating and a preparation method of the coating. The coating comprises the following components in percentage by weight: 70-75% of ethyl alcohol, 5-10% of isopropanol, 10-25% of a siloxane oligomer and the balance of ethereal sulfate. The preparation method of the coating comprises the following steps: fully mixing the components to obtain a solution and wiping the surface of the glass by using a solution-containing non-woven fabric; placing the glass, and repeatedly wiping the surface by using the same non-woven fabric in a ring manner; then removing the residual solution on the surface of the glass by using a clean non-woven fabric, subsequently polishing the surface of the material, leaving the polished surface to stand, and then obtaining the coating on the surface of the glass. According to the invention, the contact angle between the coating and water is increased, so that the drainage effect is remarkably improved; only little water is needed for washing the coating; besides, the sliding angle of the water is reduced, so that the surface of the glass is more easy to wipe; the use of harmful cleaning agents is eliminated; the nano hydrophobic and oleophobic coating has a good application prospect.

Description

technical field [0001] The invention belongs to the field of self-cleaning glass films, in particular to a nano-hydrophobic and oleophobic coating and a preparation method thereof. Background technique [0002] From the moment of production, glass has been exposed to the air. Dust, moisture, acid and alkali and physical attack in the air will cause damage to glass. In the construction industry, automobile industry and people's daily life, the problem of stains in glass hazards has increasingly become the focus of attention. Under this trend, self-cleaning glass has emerged as the times require. Self-cleaning glass refers to ordinary glass that is treated by special physical or chemical methods to produce unique physical properties on the surface, so that the glass can no longer be kept clean for a long time by traditional manual scrubbing methods. Self-cleaning glass can be divided into hydrophilic self-cleaning glass and hydrophobic self-cleaning glass according to hydroph...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C03C17/30
CPCC03C17/008C03C2217/40C03C2217/76
Inventor 戴俊慧
Owner 宁波华尔克应用材料有限公司
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