Secondary black liquor treatment method

A treatment method and black liquor technology, applied in water/sewage treatment, aerobic process treatment, anaerobic digestion treatment, etc., can solve the problems of large output of secondary black liquor, waste of raw material resources for treatment, high energy consumption, etc.

Active Publication Date: 2017-02-22
CHINA XUAN PAPER
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, most enterprises still directly introduce secondary black liquor into the concentrated black liquor treatment system for treatment, but compared with concentrated black liquor, there are significant differences in waste components and concentrations in secondary black liquor, and the output of secondary black liquor Therefore, it is undoubtedly a waste of a large amount of processing raw material resources when using a concentrated black liquor treatment system, and the energy consumption is high. Therefore, it is very important for enterprises to actively develop and research a method that can reduce the treatment cost of secondary black liquor. important

Method used

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  • Secondary black liquor treatment method

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Effect test

Embodiment 1

[0017] 1) if figure 1 As shown, the daily processing capacity of the secondary black liquor produced by washing sandalwood bark is 300m 3 In this method, the secondary black liquor is introduced into the acidic regulating tank 10, then in the acidic regulating pond 10, concentrated sulfuric acid is added until the pH value of the secondary black liquor is 3-4, and the acidified secondary black liquor is obtained;

[0018] 2) The acidified secondary black liquor is sent to the liquid inlet 21 in the anaerobic reactor 20 through the water pump 70. Under the condition of 20-25°C, the secondary black liquor contacts with the anaerobic bacteria in the anaerobic reactor 20 to undergo a biochemical degradation reaction, The sewage produced by the biochemical reaction is discharged from the liquid outlet 22 of the anaerobic reactor 20 and enters the neutral adjustment tank 30, and sodium hydroxide solution is added to the neutral adjustment tank 30 to adjust the pH value of the sewage...

Embodiment 2

[0023] 1) if figure 1 As shown, the daily processing capacity of the secondary black liquor produced by washing sandalwood bark is 300m 3 In this method, the secondary black liquor is introduced into the acid regulating tank 10, and then in the acid regulating pond 10, concentrated sulfuric acid is added until the pH value of the secondary black liquor is 3-4 to obtain acidified secondary black liquor;

[0024] 2) The acidified secondary black liquor is sent to the liquid inlet 21 in the anaerobic reactor 20 through the water pump 70. Under the condition of 20-25°C, the secondary black liquor contacts with the anaerobic bacteria in the anaerobic reactor 20 to undergo a biochemical degradation reaction, The sewage produced by the biochemical reaction is discharged from the liquid outlet 22 of the anaerobic reactor 20 and enters the neutral adjustment tank 30, and sodium hydroxide solution is added to the neutral adjustment tank 30 to adjust the pH value of the sewage to 7-8. T...

Embodiment 3

[0028] 1) if figure 1 As shown, the daily processing capacity of the secondary black liquor produced by washing sandalwood bark is 300m 3 In this method, the secondary black liquor is introduced into the acidic regulating tank 10, then in the acidic regulating pond 10, concentrated sulfuric acid is added until the pH value of the secondary black liquor is 3-4, and the acidified secondary black liquor is obtained;

[0029] 2) The acidified secondary black liquor is sent to the liquid inlet 21 in the anaerobic reactor 20 through the water pump 70. Under the condition of 20-25°C, the secondary black liquor contacts with the anaerobic bacteria in the anaerobic reactor 20 to undergo a biochemical degradation reaction, The sewage produced by the biochemical reaction is discharged from the liquid outlet 22 of the anaerobic reactor 20 and enters the neutral adjustment tank 30, and sodium hydroxide solution is added to the neutral adjustment tank 30 to adjust the pH value of the sewage...

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Abstract

The invention discloses a treatment method for secondary black liquor. The treatment method comprises the following steps: (a) regulating the pH value of the secondary black liquor to be 3-4 to obtain acidified secondary black liquor; (b) putting the acidified secondary black liquor into an anaerobic reactor, performing a biochemical treatment at normal temperature, and then regulating the pH value of the sewage generated by the biochemical treatment to be 7-8; (c) adding a coagulant into the sewage obtained in the step (b) according to a mass ratio of 1000:(0.5-1.5), stirring, primarily precipitating for 6-10 hours, and then filtering the supernatant clear liquor. The secondary black liquor is regulated to be acidic, so that a part of lignin in the secondary black liquor can be separated out; besides, by the effect of the coagulant, tiny suspension particles and colloid ions in the sewage can be aggregated, flocculated and statically precipitated; while the supernatant clear liquor is subjected to biochemical aeration treatment to generate fresh water, and the fresh water can reach emission standards after being precipitated. The treatment method for the secondary black liquor, disclosed by the invention, is simple in process, easy to control on technological condition, low in energy consumption and suitable for promotion and application in rice paper processing enterprises.

Description

technical field [0001] The invention relates to the field of rice paper processing, in particular to a method for processing secondary black liquor. Background technique [0002] Xuan paper is a traditional handicraft, and its production process includes cooking, beating, fishing, drying, paper-cutting and other processes. Among them, cooking is mainly to put sandalwood bark, the raw material of rice paper processing, in a medicinal solution to remove the lignin in the sandalwood bark. Yes, the cooking wastewater after cooking the sandalwood bark is black, which is called thick black liquor by people in the industry. In addition, the steamed sandalwood bark needs to be washed with water, and the color of the wastewater produced after washing the sandalwood bark is lighter than that of the black liquor wastewater, so It is generally referred to as sub-black liquor, which is rich in lignin and other organic wastes, so it needs to be treated in order to meet the emission standa...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F9/14C02F103/28
CPCC02F1/5236C02F1/56C02F1/66C02F1/76C02F3/02C02F3/28C02F9/00C02F2103/28
Inventor 胡文军朱大国罗鸣许志宏刘蒙胡国辉张九玲
Owner CHINA XUAN PAPER
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