Method for manufacturing organic capacitive touch screen
A technology of capacitive touch screen and manufacturing method, which is applied in the direction of electrical digital data processing, input/output process of data processing, instruments, etc., and can solve problems such as inability to realize touch screen function, low touch sensitivity, and insufficient capacitance change
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Embodiment 1
[0042] (1) Synthesis of 3,3',5,5'-tetraethynyl-1,1'-diadamantane
[0043]14 g (0.6 mol) of metallic sodium and 600 mL of n-octane were added to a 1000 mL four-necked flask equipped with a thermometer, a stirrer, and a reflux tube, and the inner temperature was cooled to 0°C. While vigorously stirring, a solution obtained by dissolving 64.5 g (0.3 mol) of 1-bromoadamantane in 300 mL of n-octane was slowly added dropwise. Drop into the medium, and keep the internal temperature at 0°C to 5°C. After the dropwise addition, if the temperature did not rise any more, the reaction was continued for 1 hour. Then, about 1500 mL of cold water was injected, and the crude product was filtered, washed with pure water, and dried. Furthermore, the crude product was recrystallized with hot hexane. The resulting recrystallized product was dried under reduced pressure to obtain 32.6 g of a product. IR analysis revealed that the absorption of the Br group (near 690-515 cm-1) disappeared, and t...
Embodiment 2
[0052] (1) Synthesis of 3,3',5,5'-tetramethyl-7,7'-diethynyl-1,1'-diamantane
[0053] In embodiment 1 (1), replace 1-bromoadamantane 64.5g (0.3mol) with 1-bromo-3,5-dimethyladamantane 72.9g (0.3mol), the amount of bromine is changed to 35g ( Except for 0.22 mol), everything else was carried out in the same manner as in Example 1 (1), to obtain 58 g of a product. According to IR analysis, the absorption of the bromine group was found to be 690-515 cm-1, and the molecular weight obtained by mass analysis was 484. From this result, it can be known that the obtained product is 3,3',5,5'-tetramethyl-7,7' -Dibromo-1,1'-diamantane.
[0054] In Example 1(1), 50 g (103 mmol) of 3,3', 5,5'-tetramethyl-7,7'-dibromo-1,1'-diamantane obtained above was used to replace 3 , 3′,5,5′-tetrabromo-1,1′-diamantane 20g (34mmol), change bromine amount 18mL (256mol) to 27.25mL (387.5mmol), and aluminum chloride (III) 3.0g (22mmol) was changed to 4.55g (33.3mmol), and all others were carried out in ...
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