Latent epoxy resin composite suitable for insulative impregnation of conformal felt and binding rope of motor and preparation method of composite
An epoxy resin and insulating impregnation technology, which is applied in the latent epoxy resin composition and its preparation, and the latent epoxy resin composition field, can solve the problems of poor temperature resistance, large material loss, poor operation manufacturability, etc. The effect of excellent electrical insulation, moderate price and suitable operation
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Embodiment 1
[0046] Add 100 parts of F-44 novolac type epoxy resin, 60 parts of E-51 double A-type epoxy resin, 30 parts of carboxy-terminated nitrile rubber modified epoxy resin (brand 861340) into the reactor, and heat to 90~ 100°C, after fully stirring evenly, add 80 parts of common solvent (ethanol: acetone = 2:1) dropwise under reflux and stirring state, after the dropwise addition is completed for 30 minutes, cool and discharge, marked as 1-A.
[0047] In a reactor, 82 parts of 2-ethyl-4-methylimidazole and 40 parts of acrylonitrile were bulk reacted at 100°C for 4 hours to prepare modified imidazole. Then 27 parts of NiCl 2 The solution composed of 90 parts of ethanol is slowly dropped into the modified imidazole to carry out the complexation reaction, the reaction process will be violently exothermic, and the temperature is controlled to be lower than 40°C. After the dropwise addition is completed, cool down to room temperature and react for 40 minutes, add 30 parts of acetic acid...
Embodiment 2
[0050] 1. Self-made polyether modified epoxy resin toughening agent
[0051] Mix 360 parts of polypropylene glycol with a molecular weight of 1000 and 100 parts of methyltetrahydrophthalic anhydride in a reactor and heat it to 140-150°C for 3 hours, then at this temperature, less than 5×10 4 The reaction was carried out for 2 hours under the vacuum environment of Pa. Add 360 parts of double A-type epoxy resin E-51 and 1 part of triphenylphosphine, and react at 150-160°C for 3 hours. After cooling, a polyether modified epoxy resin is obtained.
[0052] 2. Add 15 parts of polyether modified epoxy resin toughening agent prepared by the above reaction in the reactor, 100 parts of E-44 bisphenol A epoxy resin, 60 parts of E-51 bisphenol A epoxy resin, Heat to 90-100°C, stir well, add 80 parts of common solvent (ethanol: acetone = 2:1) dropwise under reflux and stirring state, cool and discharge after 30 minutes after the dropwise addition, marked as 2-A.
[0053] 2-A and 1-B pre...
Embodiment 3
[0055] In the reactor, 60 parts of E-44 double parts of A-type epoxy resin, 40 parts of E-51 double parts of A-type epoxy resin, 60 parts of E-20 double parts of A-type epoxy resin, and 40 parts of polyurethane modified ring Oxygen resin (brand HyPox UA10), heated to 90-100°C, fully stirred evenly, and 100 parts of common solvent (ethanol: acetone = 2:1) was added dropwise under reflux stirring state. After the dropwise addition was completed for 30 minutes, the material was cooled and discharged, which was marked as 3-A.
[0056] 3-A and 1-B prepared in Example 1 were formulated into impregnating glue at a weight ratio of 10:1. The gelation time at 120°C is 23 minutes. The conformable felt and binding rope are impregnated with glue and then dried at 40°C. The obtained conformable felt and binding rope are relatively hard, and epoxy powder will fall off when bent. The impregnation glue is vacuum removed at room temperature, cured at 100°C for 18 hours, the glass transition t...
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