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Polyisobutene butenedioic acid ester and preparation method thereof as well as minimal quantity lubricating oil prepared from polyisobutene butenedioic acid ester

A technology of polyisobutylene succinate and butylene dioic acid, which is applied in the field of lubrication to achieve the effects of saving cost, low pollution, and saving solvent input

Active Publication Date: 2014-02-26
湖南润捷科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the lubricant has good lubricating properties, the use of a large proportion of sulfides, chlorides, phosphides, etc. will bring greater pressure to the environment

Method used

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  • Polyisobutene butenedioic acid ester and preparation method thereof as well as minimal quantity lubricating oil prepared from polyisobutene butenedioic acid ester
  • Polyisobutene butenedioic acid ester and preparation method thereof as well as minimal quantity lubricating oil prepared from polyisobutene butenedioic acid ester
  • Polyisobutene butenedioic acid ester and preparation method thereof as well as minimal quantity lubricating oil prepared from polyisobutene butenedioic acid ester

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0046] 1# micro-quantity lubricating oil

[0047] Step 1: Put 148.24kg (2000mol) of isobutanol and 98.06kg (1000mol) of maleic anhydride (butenedioic anhydride) into the polymerization kettle respectively, and stir thoroughly;

[0048] Step 2: Put 0.74kg of initiator dibenzoyl peroxide (BPO) into the polymerization kettle;

[0049] Step 3: Filling with nitrogen to discharge the air in the polymerization kettle;

[0050] Step 4: heat up to 80°C while stirring;

[0051] Step 5: Slowly fill 56.11kg (1000mol) of isobutylene gas into the mixed liquid in the polymerization kettle, and keep stirring at a constant temperature;

[0052] Step 6: Keep stirring at constant temperature for 12 hours after filling the isobutene gas;

[0053] Step 7: Add 6 kg of catalyst cation exchange resin to the polymerization kettle;

[0054] Step 8: heat up to 200°C, fully stir and react for 3 hours;

[0055] Step 9: remove moisture and unreacted isobutanol under reduced pressure;

[0056] Step te...

Embodiment 2

[0067] 2# Minimal quantity lubricating oil

[0068] Step 1: Put 192.71kg (2600mol) of n-butanol and 116.07kg (1000mol) of maleic acid (maleic acid) into the polymerization kettle respectively, and fully stir;

[0069] Step 2: Put 0.62kg of initiator dibenzoyl peroxide (BPO) into the polymerization kettle;

[0070] Step 3: Filling with nitrogen to discharge the air in the polymerization kettle;

[0071] Step 4: heat up to 76°C while stirring;

[0072] Step 5: Slowly fill 56.11kg (1000mol) of isobutylene gas into the mixed liquid in the polymerization kettle, and keep stirring at a constant temperature;

[0073] Step 6: Keep stirring at constant temperature for 10 hours after filling the isobutene gas;

[0074] Step 7: Add 5 kg of catalyst cation exchange resin to the polymerization kettle;

[0075] Step 8: heat up to 185°C, fully stir and react for 3.6 hours;

[0076] Step 9: remove moisture under reduced pressure, unreacted n-butanol;

[0077] Step ten: remove the cation...

Embodiment 3

[0085] 3# micro lubricant

[0086] Step 1: Put 138.21kg (3000mol) of ethanol and 116.07kg (1000mol) of maleic acid into the polymerization kettle respectively, and fully stir;

[0087] Step 2: Put 0.51kg initiator diethylhexyl peroxydicarbonate (EHP) into the polymerization kettle;

[0088] Step 3: Filling with nitrogen to discharge the air in the polymerization kettle;

[0089] Step 4: heat up to 70°C while stirring;

[0090] Step 5: Slowly fill 56.11kg (1000mol) of isobutylene gas into the mixed liquid in the polymerization kettle, and keep stirring at a constant temperature;

[0091] Step 6: Keep stirring at constant temperature for 6 hours after filling the isobutene gas;

[0092] Step 7: Add 3.1 kg of catalyst cation exchange resin to the polymerization kettle;

[0093] Step 8: heat up to 180°C, fully stir and react for 4 hours;

[0094] Step 9: remove moisture and unreacted ethanol under reduced pressure;

[0095] Step ten: remove the cation exchange resin, which i...

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PUM

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Abstract

The invention provides polyisobutene butenedioic acid ester and a preparation method thereof. The chemical structure of the polyisobutene butenedioic acid ester is as shown in specification. The polyisobutene butenedioic acid ester provided by the invention has good lubricity and extreme pressure anti-wear property and can be used for replacing added components such as chlorides, sulfides and phosphides which are harmful for environments in conventional fields. Minimal quantity lubricating oil prepared from the polyisobutene butenedioic acid ester has good lubricity and extreme pressure anti-wear property. A very small quantity of minimal quantity lubricating oil can meet the high-end requirements of metal processing; the damage to environments and workers is reduced; the pollution to environments is minimized.

Description

technical field [0001] The invention relates to the field of lubricating technology, in particular to polyisobutylene butadiene ester and its preparation method and the preparation of micro-quantity lubricating oil by using the polyester. Background technique [0002] Cutting oils, coolants, emulsions and other lubricants used in traditional metal processing lubrication and cooling are used in large quantities, and traditional cutting oils use mineral oil as the base oil, which is not easy to decompose in the natural environment, and most of the additives used are harmful to the human body. Harmful to the environment, it not only wastes resources, but also causes huge pollution of processing sites and the environment. In recent years, the research on micro-cutting technology has made great progress, which has reduced the harm caused by the discharge of a large amount of cutting oil to the environment. However, in order to solve the problem of micro-cutting, excessive amounts...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F222/06C08F222/02C08F210/10C08F8/14C10M145/16C10N30/06C10N40/22
Inventor 张乃庆吴启东
Owner 湖南润捷科技有限公司
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