Compound expanding agent for inhibiting temperature rising in early stage and promoting hydration in later stage and preparation method thereof

A composite expansion agent and temperature rise technology, applied in the field of building materials, can solve problems such as low water-to-binder ratio, large hydration temperature rise, temperature cracks, etc., achieving good environmental compatibility, sustainable expansion and long-term compensation, drying shrinkage Effect

Active Publication Date: 2013-12-11
WUHAN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the current steel pipe concrete materials generally have high strength grades, a large amount of cementitious materials, and a low water-binder ratio, and are in an environment where the steel pipes are closed and unable to exchange water with the outside world. The hydration is limited, it is difficult to maintain stable expansion, and it is easy to cause the phenomenon of "voiding" between the concrete and the steel pipe, which will damage the integrity of the structure and greatly affect its bearing capacity and service life; while the cement water in mass concrete The heat of hydration is not easy to dissipate, and the temperature rise of hydration is large, which makes the temperature difference between the inner and outer surfaces of the concrete large, which is easy to cause uneven temperature deformation and temperature stress, thus causing temperature cracks and affecting its durability.
Although adding expansion agent to mass concrete can compensate its self-shrinkage and drying shrinkage, the expansion agent generally hydrates quickly in the early stage and releases heat rapidly, which is not conducive to controlling its hydration temperature rise to avoid the appearance of temperature cracks

Method used

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  • Compound expanding agent for inhibiting temperature rising in early stage and promoting hydration in later stage and preparation method thereof
  • Compound expanding agent for inhibiting temperature rising in early stage and promoting hydration in later stage and preparation method thereof
  • Compound expanding agent for inhibiting temperature rising in early stage and promoting hydration in later stage and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1~5

[0034] A composite expansion agent that suppresses temperature rise in the early stage and promotes hydration in the later stage, the preparation process of which comprises the following steps:

[0035] (1) Weigh each component: calcium oxide, sulphoaluminate cement clinker, anhydrite, magnesium oxide, boric acid, zinc sulfate, and ICA, the mass percentage of each component is shown in Table 1 below; (2) Calcium oxide , sulphoaluminate cement clinker and anhydrite are mixed and ground to a specific surface area ≥ 280m 2 / kg; (3) Separately grind magnesium oxide to a specific surface area ≥ 450m 2 / kg; (4) Mix and homogenize the materials obtained in step 2) and step 3) with other materials remaining in step 1) to obtain the composite expansion agent, and pack it for storage.

[0036] The calcium oxide is light-burned calcium oxide, which is calcite calcite after being crushed and calcined at a high temperature of 900-1100°C;

[0037] The sulphoaluminate cement clinker is mad...

Embodiment 4

[0051] In Example 4, the preparation method of the ICA is roughly the same as that of Examples 1-3, the difference being: (1) The mass of cassava starch weighed is 1 g; (2) The weighed ammonium cerium nitrate and ammonium persulfate (3) The mass of the monomer acrylamide weighed is 0.1g, the mass of bismethacrylamide is 0.01g, the temperature of the graft copolymerization reaction is 50°C, and the dropping time of the monomer solution (4) The mass ratio of 2-acrylamide-2-methylpropanesulfonic acid to monomer acrylamide is 1:1, the stirring speed of composite crosslinking is 80r / min, and the reaction temperature is 50°C. The time is 2.5h; (5) Hydrolysis: adjust the pH value to 10.

Embodiment 5

[0052] In Example 5, the preparation method of the ICA is roughly the same as that of Examples 1-3, the difference being: (1) the mass of tapioca starch weighed is 4g; (2) the weighed ammonium cerium nitrate and ammonium persulfate (3) The mass of the monomer acrylamide weighed is 10g, the mass of bismethacrylamide is 0.05g, the temperature of the graft copolymerization reaction is 80°C, and the dropping time of the monomer solution is 0.7h; (4) The mass ratio of 2-acrylamide-2-methylpropanesulfonic acid to monomer acrylamide is 1:9, the stirring speed of composite crosslinking is 90r / min, the reaction temperature is 80℃, and the reaction time (5) Hydrolysis: adjust the pH value to 11.

[0053] Table 1 The percentage of each component of the composite expansion agent (%)

[0054] Example

Calcium Oxide

Sulphoaluminate cement clinker

Anhydrite

MgO

boric acid

Zinc sulfate

ICA

1

10

43

35

10

0.3

1.5

0.2

...

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Abstract

The invention belongs to the field of building material, and particularly relates to a compound expanding agent for inhibiting temperature rising in the early stage and promoting hydration in the later stage. The compound expanding agent comprises the following raw materials by weight: 10 to 30 % of calcium oxide, 28 to 43 % of sulphate aluminium cement clinker, 25 to 40 % of anhydrite, 5 to 15 % of magnesium oxide, 0.3 to 0.5 % of boric acid, 1 to 1.5 % of zinc sulfate and 0.2 to 0.5 % of ICA. The compound expanding agent has the advantages of high early stage expanding capacity, sustainable expansion and long expanding stable period, can effectively compensate self-constriction and drying shrinkage of concrete, enables the synergetic development of the volume expansion and the strength increase of concrete, and is very suitable for being applied to steel pipe concrete and mass concrete.

Description

technical field [0001] The invention belongs to the field of building materials, and in particular relates to a composite expansion agent capable of suppressing temperature rise at an early stage and promoting hydration at a later stage and a preparation method thereof. Background technique [0002] Due to the continuous improvement of modern material preparation level and building construction technology, the construction of super high-rise buildings and long-span steel pipe arch bridges has become more and more popular, so the engineering applications of steel pipe concrete and mass concrete are very frequent. However, the current steel pipe concrete materials generally have high strength grades, a large amount of cementitious materials, and a low water-binder ratio, and are in an environment where the steel pipes are closed and unable to exchange water with the outside world. The hydration is limited, it is difficult to maintain stable expansion, and it is easy to cause t...

Claims

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Application Information

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IPC IPC(8): C04B28/14C04B22/14C04B22/06
Inventor 丁庆军漆春生牟廷敏洪斌崔洪海苗强聂传振胡曙光黄修林
Owner WUHAN UNIV OF TECH
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