Colorant Dispersion liquid
A coloring agent and dispersion liquid technology, applied in the direction of instruments, polarizing elements, optical mechanical equipment, etc., can solve the problem that the brightness of the color filter is very satisfactory, and achieve the effect of high brightness
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[0366] Hereinafter, examples are cited, and the present invention is further described in detail, but the present invention is not limited by the following examples, and can be appropriately changed within the scope of the above-mentioned and following purposes, and they are also included in the technology of the present invention. in range. Unless otherwise specified, "%" and "part" in an example are mass % and a mass part.
[0367] In the following synthesis examples, the compounds were identified by mass spectrometry (LC: 1200 model manufactured by Agilent, MASS: LC / MSD model manufactured by Agilent).
Synthetic example 1
[0369] 20 parts of the compound represented by the formula (1x) and 200 parts of N-ethyl-o-toluidine (manufactured by Wako Pure Chemical Industries, Ltd.) were mixed under light-shielding conditions, and the resulting solution was stirred at 110° C. for 6 hours. After cooling the obtained reaction liquid to room temperature, this was added to the mixed liquid of 800 parts of water and 50 parts of 35 weight% hydrochloric acid, and it stirred at room temperature for 1 hour, and crystallization precipitated. The precipitated crystals were collected as suction-filtered residues and dried to obtain 24 parts of the compound represented by the formula (1-24). The yield was 80%.
[0370]
[0371] Identification of compounds represented by formula (1-24)
[0372] (mass analysis) ionization mode = ESI+: m / z = [M+H] + 603.4
[0373] Exact Mass: 602.2
[0374] [Synthesis Example 2]
[0375] A compound represented by the formula (1-32) was obtained in the same manner as in Synthesis...
Synthetic example 10
[0413] Nitrogen was flowed into a flask equipped with a stirrer, a thermometer, a reflux cooler, and a dropping funnel at 0.02 L / min to make a nitrogen atmosphere, 305 parts of propylene glycol monomethyl ether acetate was added, and it was heated to 70° C. while stirring. Next, 60 parts of acrylic acid, 3,4-epoxytricyclo[5.2.1.0 2,6 ] Decyl acrylate (the compound shown in the formula (I-1) and the compound shown in the formula (II-1) are mixed in a molar ratio of 50:50.) 440 parts are dissolved in propylene glycol monomethyl ether acetate 140 A solution was prepared in portions, and the solution was dropped into a flask kept at 70° C. using a dropping funnel over 4 hours.
[0414]
[0415] On the other hand, 30 parts of polymerization initiator 2,2'-azobis(2,4-dimethylvaleronitrile) was dissolved in 225 parts of propylene glycol monomethyl ether acetate over 4 hours using another dropping funnel. The resulting solution was added dropwise to the flask. After the dropwise ...
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