ECF bleaching technology of fast growing poplar by sodium hydroxide anthraquinone pulp bio-chemical method

A sodium hydroxide anthracene, biochemical technology, applied in the field of papermaking, can solve problems such as large-scale application that has not yet been realized, and achieve the effects of environmental protection, low kappa value, and consumption reduction

Active Publication Date: 2013-09-25
QILU UNIV OF TECH
View PDF2 Cites 6 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] At present, there are many studies on the application of xylanase in the bleaching of hardwood kraft pulp, and some industrialization has been realized abroad, but large-scale application has not yet been realized in China.
At the same time, there are few reports on the technology and mechanism of xylanase used in sodium hydroxide anthraquinone pulp bleaching

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • ECF bleaching technology of fast growing poplar by sodium hydroxide anthraquinone pulp bio-chemical method
  • ECF bleaching technology of fast growing poplar by sodium hydroxide anthraquinone pulp bio-chemical method
  • ECF bleaching technology of fast growing poplar by sodium hydroxide anthraquinone pulp bio-chemical method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] Example 1 Process optimization of xylanase treatment of fast-growing poplar NaOH-AQ pulp

[0033] There are many studies on the assisted bleaching of hardwood KP pulp by xylanase, and good results have been achieved. According to relevant literature, the main factors affecting the treatment of pulp with xylanase are enzyme dosage, temperature, pH value and time, etc. These factors have varying degrees of influence on the effect of oxygen delignification and subsequent bleaching. At present, since the research on xylanase in the bleaching of fast-growing poplar NaOH-AQ pulp is rarely reported, it is necessary to explore the most suitable process conditions for pretreatment of fast-growing poplar NaOH-AQ pulp with different xylanase preparations, and use a variety of modern instruments It is of great innovative and practical significance to explore the bleaching-assisting mechanism of the new xylanase on NaOH-AQ pulp of fast-growing poplar by using analytical means.

[0...

Embodiment 2

[0106] Example 2 Optimization of bleaching process conditions

[0107] 2.1.1 Raw materials

[0108] The fast-growing poplar chips used in the experiment were mixed fast-growing poplar chips, which were obtained from Shandong Sun Paper Co., Ltd. The length of the wood chips is 15-25mm, the width is 10-20mm, and the thickness is 3-5mm. The qualified rate of the wood chips is over 90%.

[0109] Xylanase X 1 Provided by Novozymes, liquid, without cellulase activity; xylanase X 2 、X 3 All are provided by Shenzhen Lvweikang Biological Co., Ltd., all are white powdery solids, and none of them contain cellulase activity.

[0110] 2.1.2 Cooking experiment

[0111] Cook in a 15L electric heating rotary cooking pot to obtain fast-growing poplar sodium hydroxide anthraquinone puree. The cooking conditions are: the amount of alkali used is 22% (for absolute dry raw materials, based on NaOH), the amount of AQ is 0.05%, the liquid ratio is 1:4, the highest cooking temperature is 165°C,...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
lengthaaaaaaaaaa
widthaaaaaaaaaa
thicknessaaaaaaaaaa
Login to view more

Abstract

The invention discloses an ECF bleaching technology of fast growing poplar by a sodium hydroxide anthraquinone pulp bio-chemical method. The ECF bleaching technology is characterized by comprising the following steps: (1) boiling: taking fast growing poplar chips, stewing the fast growing poplar chips in a digester to obtain virgin pulp, washing, and screening to obtain paper pulp; (2) xylanase pretreatment; and (3) ECF bleaching: bleaching the above paper pulp which has undergone enzyme treatment, wherein the bleaching process is one of three bleaching processes, namely ODQP, OPDQP or O1O2PDQP. According to the invention, xylanase is used to pretreat the paper pulp, and one of the three bleaching processes, namely ODQP, OPDQP or O1O2PDQP, is carried out for bleaching so as to obtain the paper pulp with higher whiteness and viscosity. In comparison with paper pulp which is directed bleached without xylanase pretreatment, the paper pulp produced by the ECF bleaching technology has the following advantages: beating whiteness loss is less, folding strength is averagely higher by 30 times, burst index is averagely higher by 0.35N.m.g<-1>, breaking length is averagely higher by 0.25KM, and tear index difference is basically unchanged or slightly reduced by a very small magnitude.

Description

technical field [0001] The invention relates to a biochemical ECF bleaching process of sodium hydroxide anthraquinone pulp of fast-growing poplar, belonging to the technical field of papermaking. Background technique [0002] Due to the production of odorous gases such as hydrogen sulfide, methyl mercaptan, methyl sulfide and dimethyl sulfide in the process of kraft pulping and alkali recovery, there are problems of pollution and air odor around the production unit. Therefore, in the open pulping production process of some medium-sized pulp mills, the pulping technology based on the sodium hydroxide anthraquinone method is adopted. Because the chemical used in sodium hydroxide anthraquinone pulping is mainly sodium hydroxide, which also contains a small amount of anthraquinone as a cooking protective agent, these two chemicals are non-toxic and odorless, and no odor is produced during the pulping and cooking process Therefore, this alkaline pulping technology is widely used...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): D21C9/14
Inventor 吉兴香陈嘉川田中建杨桂花庞志强
Owner QILU UNIV OF TECH
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap