Method for reducing over electroplating on surface of wafer after through silicon via (TSV) is electroplated with copper
A technology of through-silicon vias and electroplating copper, which is applied in the direction of circuits, electrical components, and electrical solid devices, and can solve problems such as copper overplating on the surface of wafers, and achieve the effects of blocking copper deposition, simple process, and cost reduction
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Embodiment 1
[0025] Such as figure 2 As shown, a sample to be plated that reduces the overplating of the wafer surface after copper plating through silicon vias includes a wafer 5, and a vertical through silicon hole 4 is etched on the surface of the wafer 5, from the inside to the surface of the wafer 5. An insulating layer 3 , a diffusion barrier layer 2 and a copper seed layer 1 are sequentially arranged outside; a special layer 6 is also arranged outside the copper seed layer 1 ; the thickness of the special layer 6 is 4-200nm.
[0026] The material of the special layer 6 is metal Ta, V, Ti, Al, Fe or non-metal TiN, TaN, AlN.
[0027] The material of the diffusion barrier layer 2 is one of Ta, Ti, Ni, TaN and TiN.
[0028] The thickness of the special layer 6 is 4-50nm.
[0029] The thicknesses of the diffusion barrier layer 2 and the copper seed layer 1 are both 10-200mm.
[0030] The height of the special layer 6 at the opening of the vertical TSV 4 is not greater than the sum of...
Embodiment 2
[0032] Such as figure 1 As shown, before the vertical through-silicon via TSV electroplating copper filling process in the present invention, a special layer 6 is made on the wafer surface and the vertical through-silicon via 4 orifices, such as figure 2 As shown, its effect is to reduce (compared to copper seed layer 1) or inhibit copper deposition of copper on the wafer surface. Specific steps are as follows:
[0033] (1) Through-hole etching: take the wafer 5, and etch vertical through-silicon holes 4 on its surface through deep reactive ion etching equipment;
[0034] (2) Preparation of the insulating layer: take the wafer 5 after the etching in step (1), and use silicon dioxide or silicon nitride to prepare the insulating layer 3 by plasma-enhanced chemical vapor deposition; a liquid reaction source is selected, The deposition temperature is 400°C, and the deposition thickness is 10nm;
[0035] (3) Preparation of the diffusion barrier layer and the copper seed layer: ...
Embodiment 3
[0040] (1) Through-hole etching: take the wafer 5, and etch vertical through-silicon holes 4 on its surface through deep reactive ion etching equipment;
[0041] (2) Preparation of the insulating layer: take the wafer 5 after the etching in step (1), and use silicon dioxide or silicon nitride to prepare the insulating layer 3 by plasma-enhanced chemical vapor deposition; a liquid reaction source is selected, The deposition temperature is 400°C, and the deposition thickness is 300nm;
[0042] (3) Preparation of the diffusion barrier layer and the copper seed layer: take the wafer 5 prepared in step (2), and deposit the diffusion barrier layer 2 on the outside of the insulating layer 3 by physical vapor deposition at a deposition temperature of 220°C; A layer of copper seed layer 1 is deposited on the outer side of the barrier layer (2) again by physical vapor deposition, and the deposition temperature is 500°C;
[0043] (4) Preparation of the special layer: take the wafer 5 ob...
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