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A kind of titanium-containing red mud composite binder and preparation method thereof

A binder and red mud technology, which is applied in the field of titanium-containing red mud composite binder and its preparation, can solve the problems of decreased total iron TFe content of finished pellets, decreased recovery rate of useful elements, and prohibitive manufacturers, to achieve The effects of high titanium content, improved pellet grade, and reduced process production cost

Active Publication Date: 2014-10-08
LAIWU IRON & STEEL GRP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The inorganic binder is mainly bentonite. Although the price of bentonite is low, the main composition of bentonite is SiO 2 and Al 2 o 3 , using bentonite as a binder to produce pellets will have adverse effects such as decreased total iron TFe content of finished pellets, increased flux addition, increased slag, decreased recovery of useful elements, increased production energy consumption, and decreased productivity.
Although the organic binder has almost no impact on the quality of the final pellets, it is often prohibitive for manufacturers because of its high price (generally ten times or more the price of bentonite)
[0004] In order to ensure full recovery of titanium and iron in ferrotitanium-containing fine powder, manufacturers often use organic binders, and to achieve the same quality green balls, the amount of organic binders is often more than that of inorganic binders. , sometimes even 2 to 3 times the amount of the inorganic binder, which puts a lot of pressure on the production cost and also leads to a reduction in production capacity

Method used

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  • A kind of titanium-containing red mud composite binder and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] Composition: TFe 21.54%, Al 2 o 3 18.56%, SiO 2 8.97%, TiO 2 7.6% of the red mud is dried with a chain grate (200°C), crushed by a ball mill, and 80% of the dry red mud powder with a particle size of less than 200 mesh is obtained; the converter fine ash with a composition of TFe 51.41% and CaO 4.81% is dried with a chain grate Dry machine drying (200°C) and ball mill crushing to obtain 80% dry converter fine ash with a particle size of less than 200 mesh; dry red mud powder and dry converter fine ash are mixed according to the mass percentage of 65:35, and the obtained titanium-containing red The composition of mud composite binder is TFe 31.99%, Al 2 o 3 12.06%, SiO 2 5.83%, TiO 2 4.94%, CaO 1.68%. After the titanium-containing red mud composite binder is used in the production of titanium-containing iron fine powder pellets, compared with calcium-based bentonite, the TFe of the pellets is increased by 1.54%, and the TiO 2 An increase of 0.15%; compared w...

Embodiment 2

[0030] Composition: TFe 40.76%, Al 2 o 3 11.48%, SiO 2 14.88%, TiO 2 6.23% of the red mud is dried with a chain grate (200°C), crushed by a ball mill, and 80% of the dry red mud powder with a particle size of less than 200 mesh is obtained; the converter fine ash with a composition of TFe 51.41% and CaO 4.81% is dried with a chain grate Dry machine drying (200°C) and ball mill crushing to obtain 80% dry converter fine ash with a particle size of less than 200 mesh; dry red mud powder and dry converter fine ash are mixed according to the mass percentage of 85:15, and the obtained titanium-containing red The composition of mud composite binder is TFe 42.35%, Al 2 o 3 9.76%, SiO 2 12.65%, TiO 2 5.29%, CaO 0.72%. After the titanium-containing red mud composite binder is used in the production of titanium-containing iron fine powder pellets, compared with calcium-based bentonite, the TFe of the pellets is increased by 2.03%, and the TiO 2 An increase of 0.16%, the eff...

example 3

[0032] Composition: TFe 40.76%, Al 2 o 3 11.48%, SiO 2 14.88%, TiO 2 6.23% of the red mud is dried with a chain grate (200°C), crushed by a ball mill, and 80% of the dry red mud powder with a particle size of less than 200 mesh is obtained; the converter fine ash with a composition of TFe 51.41% and CaO 4.81% is dried with a chain grate Dry machine drying (200°C) and ball mill crushing to obtain 80% dry converter fine ash with a particle size of less than 200 mesh; dry red mud powder and dry converter fine ash are mixed according to the mass percentage of 95:5, and the obtained titanium-containing red The composition of mud composite binder is TFe 41.29%, Al 2 o3 10.91%, SiO 2 14.14%, TiO 2 5.92%, CaO 0.24%. After the titanium-containing red mud composite binder is used in the production of titanium-containing iron fine powder pellets, compared with calcium-based bentonite, the TFe of the pellets is increased by 1.98%, and the TiO 2 An increase of 0.18%, the effec...

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Abstract

The invention relates to a titaniferous red mud compound binder and a preparation method thereof. The titaniferous red mud compound binder is prepared by selecting, drying, crushing and uniformly mixing waste red mud of aluminium manufactures and fine ash of converters of iron and steel plants according to a ratio of (65%-95%):(5%-35%). The prepared titaniferous red mud compound binder is mainly used for granulating titanium and iron-containing concentrate, has the characteristics of good binding effect, low price, high iron and titanium contents and the like, and can partially or completely be used for substituting for conventional organic binders and inorganic binders to produce titanium and iron-containing concentrate pellets. Compared with the organic binder which is used for completely producing the titanium and iron-containing concentrate pellets, the compound binder is greatly lowered in production cost, and iron and titanium elements in the red mud and fine ash of the converters can be effectively recycled. Compared with the inorganic binder which is used in the whole process, the compound binder is improved in pellet grade.

Description

technical field [0001] The invention relates to the technical fields of chemical industry and metallurgy industry, in particular, the invention relates to a titanium-containing red mud composite binder and a preparation method thereof. Background technique [0002] With the development of the iron and steel industry, people have been able to process titanium-containing iron fine powder through the melting process, so that the titanium and iron elements in the ore can be effectively recovered. The current process of treating ferro-titanium fine powder is generally the first process of mixing, that is, mixing ferro-titanium fine powder, flux, binder, etc., and the binder is an indispensable and important part of the process. It should have good ball forming ability so that the pellets made have good performance. At present, the binders that have been used mainly include inorganic binders, such as bentonite, water glass, slaked lime, cement, clay, etc.; organic binders, such a...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22B1/243
Inventor 李建云曾晖吴允巩国志杜春峰王金洪董丙成吕霞
Owner LAIWU IRON & STEEL GRP
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