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Electrospun micro-nanofiber reinforced aerogel flexible thermal insulation material and its preparation method

A flexible and fiber-reinforced airgel technology, applied in the field of thermal insulation materials, can solve the problem of affecting the mechanical structure stability of fiber/aerogel composite materials, increasing the gas phase thermal conductivity of composite materials, and reducing the thermal insulation performance of composite materials, etc. problems, to achieve the effect of reducing interface bonding defects, increasing gas thermal resistance and convective heat transfer resistance, and improving thermal energy utilization efficiency

Active Publication Date: 2013-05-15
吴会军
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Problems solved by technology

Compared with the brittleness of the inorganic fiber component, due to the flexibility of the polymer fiber itself, using polymer fiber as a reinforcing phase to improve the mechanical properties of airgel, especially the flexibility, has achieved remarkable results, but similar to the larger diameter of the inorganic fiber, the polymer fiber The diameter (about tens of microns) is much larger than the nanopore diameter of airgel, and it is easy to produce cracks in the drying process of the fiber / aerogel composite gel, which not only affects the mechanical structure stability of the fiber / aerogel composite, but also Increasing the gas-phase thermal conductivity of the composite material reduces the thermal insulation performance of the composite material; in addition, the polymer fiber has a poor effect on infrared composite shielding in the high temperature section, and the polymer fiber / aerogel composite material has a large thermal conductivity in the high temperature section

Method used

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  • Electrospun micro-nanofiber reinforced aerogel flexible thermal insulation material and its preparation method

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Embodiment Construction

[0038] The electrospun micro-nano fiber reinforced airgel flexible thermal insulation material of this embodiment is composed of PVDF (polyvinylidene fluoride) electrospun micro-nano fiber felt and SiO with high thermal insulation performance. 2 airgel composite.

[0039] The preparation steps of electrospun PVDF micro-nano fiber felt are as follows:

[0040] (1) Add PVDF particles to DMF (N,N-dimethylformamide solvent), in which the mass concentration of PVDF is 25%, and stir in a constant temperature water bath at 65°C until PVDF is completely dissolved;

[0041] (2) Using an electrospinning device, the spinning process parameters are: injection speed 0.03~0.04mm min -1 , voltage 12KV, drum receiver distance 15cm, drum running speed 4m·min -1 , the lateral movement speed of the syringe is 12cm·min -1 ;

[0042] (3) Inject the mixture of PVDF and DMF into the syringe, fix it on the metering pump for spinning, and make an electrospun micro-nano fiber mat with a certain thick...

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Abstract

Belonging to the field of heat preservation and thermal insulation materials, the invention puts forward an electrospun micro-nanofiber reinforced aerogel flexible thermal insulation material and its preparation method. The method takes electrospun micro-nanofiber as a reinforcement body, which is mixed with an SiO2 sol. A sol-gel process is employed to prepare an electrospun micro-nanofiber and aerogel composite thermal insulation material with a stable structure under normal temperature and pressure conditions. The method provided in the invention employs micro-nanoscale electrospun micro-nanofiber to reinforce the aerogel, so that the composite material can have better flexibility, interface bonding property and structural integrity. While the mechanical properties of the aerogel thermal insulation composite material are improved, the material also can maintain good thermal insulation performance.

Description

technical field [0001] The invention relates to an airgel flexible thermal insulation material reinforced by electrospun micro-nano fibers, which belongs to the field of thermal insulation materials. Background technique [0002] With the development of economy and society, human beings have an increasing demand for energy, but with the massive exploitation of fossil energy, the reserves continue to decline, and it is urgent for human beings to seek new energy and improve energy utilization. On the long way to seek new energy, people have devoted a lot of energy to research on how to improve energy utilization, and thermal insulation materials have become one of the research directions that cannot be ignored. It can effectively reduce the heat exchange between the medium and its environment, and is widely used in building materials, energy storage equipment, aerospace vehicles, and thermal insulation clothing. [0003] Airgel is the solid substance with the lowest density a...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B28/24C04B16/06
Inventor 吴会军陈奇良丁云飞周孝清
Owner 吴会军
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