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Concrete modifier and concrete

A concrete modifier and concrete technology, which is applied in the field of building materials, can solve the problems of increasing the water consumption of concrete mixture, increasing the resistivity of concrete, and large water demand of graphite powder, so as to achieve the effect of improving electrical performance and improving the resistance to resistance. The effect of improving permeability and dispersibility

Active Publication Date: 2014-12-10
STATE GRID CHONGQING ELECTRIC POWER CO ELECTRIC POWER RES INST
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Graphite has good electrical conductivity (the carbon content is greater than 80%, and its resistivity is usually not greater than 0.5Ω·cm). Compared with copper powder, iron powder, aluminum powder and other metal powders, it has stable chemical properties, acid and alkali resistance, Good oxidation resistance and other advantages, but the graphite powder needs to be mixed with a higher amount to form an interconnected conductive network in the concrete matrix, and the water demand of the graphite powder is very large, and the water consumption of the concrete mixture needs to be greatly increased. As a result, the strength of concrete decreases rapidly with the increase of graphite powder content.
[0006] Steel fibers have the advantages of improving the mechanical properties of concrete such as tensile, bending, and shearing resistance. At the same time, as metals, they can also perform their conductive functions. However, as time goes by, due to the high alkaline environment of steel fiber concrete, metal It is easy to produce a passivation film, resulting in a significant increase in the resistivity of the concrete

Method used

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Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0036] The concrete modifier of the present invention can be prepared according to a method well known to those skilled in the art, and there is no special restriction. The present invention is preferably prepared according to the following method: 10 to 80 parts by weight of carbon nanotubes, 2 to 7 parts by weight of cement and / or the main material of cement and 5 to 10 parts by weight of acrylic emulsion are mixed and stirred, and dried after mixing. , Grind into powder to obtain concrete modifier. The drying is preferably vacuum drying, the drying temperature is preferably 100°C to 140°C, and the drying time is preferably 40 to 60 hours. In the present invention, it is preferable to add 1 to 15 parts by weight of carbon black.

[0037] The carbon nanotubes, cement and / or the main material of cement, acrylic emulsion and carbon black are all the same as those described above, and will not be repeated here.

[0038] The present invention also provides a concrete, including the ...

Embodiment 1

[0044] Mix 75 parts by weight of carbon nanotubes, 10 parts by weight of carbon black, 5 parts by weight of silicate and 10 parts by weight of acrylic emulsion, add them to a high-speed mixer and mix them thoroughly, and put them in a vacuum drying oven after mixing. It was dried at ℃ for 48h and ground into powder to obtain concrete modifier.

Embodiment 2

[0046] Dissolve 20 parts by weight of the waterproof emulsion in water, add 60 parts by weight of cement and 7 parts by weight of the concrete modifier obtained in Example 1, stir at 300r / min for 10 minutes, and then add 50 parts by weight of river sand. Continue to stir at 300r / min for 10 minutes, cast into a film, and cure for 30 days under standard curing conditions to obtain concrete.

[0047] The concrete obtained in Example 2 was tested with a concrete resistivity tester, and the resistivity was 0.52Ω·m in the wet state and 1.64Ω·m in the dry state.

[0048] The concrete obtained in Example 2 was tested according to GB / T19856.1, and the impulse current resistance ΔR%=2.7% was obtained.

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PUM

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Abstract

The invention provides a concrete modifier, comprising 10-80 weight parts of carbon nanotubes, 2-7 weight parts of cement and / or a cement raw material and 5-10 weight parts of an acrylic emulsion. Compared with graphite powder modifier and steel fiber modifier in the prior art, the invention has the following advantages: first, the invention uses the carbon nanotubes as the main electrical property modifier, which can realize good electrical performance improvement with small addition amount, and has little impact on mechanical properties and impulse current withstand performance of the concrete; second, after the reaction, the acrylic emulsion can gradually produce acrylic resin to fill gaps within the concrete, improve impermeability of the concrete, and high tenacity of the acrylic resin endows the conductive concrete with strong mechanical properties; and third, addition of the cement and / or the cement main material into the modifier can improve dispersion of the carbon nanotubes and compatibility of the carbon nanotubes with the main material of the concrete.

Description

Technical field [0001] The invention belongs to the technical field of building materials, and particularly relates to a concrete modifier and concrete. Background technique [0002] Concrete has a history of more than 100 years, and it has become the most widely used and most used building material in the field of civil engineering worldwide. Under normal circumstances, ordinary concrete has a high resistivity and is a poor conductor of electricity. In the case of conductive concrete, a certain amount of conductive component material is added to ordinary concrete. It is a new type of cement-based composite material that is mixed and condensed by cementing materials, conductive materials, dielectric aggregates and water in a certain proportion. New concrete with specified electrical properties and certain mechanical properties. Conductive concrete not only has the characteristics of structural materials, but also has electrical conductivity and smart characteristics, making con...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B24/26C04B22/02
Inventor 李勇王谦吴高林伏进陈超杨雁逄凯陈伟肖前波张世海
Owner STATE GRID CHONGQING ELECTRIC POWER CO ELECTRIC POWER RES INST
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