Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Self-breathing direct methanol fuel cell

A methanol fuel cell and self-breathing technology, applied in fuel cells, fuel cell additives, fuel cell components, etc., can solve the problems of the anode being easily oxidized by air and reducing the stability of the battery, so as to prevent the anode from being oxidized , long discharge time and stable performance

Active Publication Date: 2013-04-24
CHANGZHOU INST OF ENERGY STORAGE MATERIALS &DEVICES
View PDF9 Cites 8 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among them, the anode support plate consists of two layers of plates hollowed out into several parallel channels and a diffused breathable membrane between the two plates. The diffused breathable membrane absorbs the methanol solution, and the methanol solution directly contacts the membrane electrode through the channels and the anode collector plate. , when the liquid level of the solution is not enough to submerge the surface of the membrane electrode, the unsubmerged part of the membrane electrode will be exposed to the air, and the anode in the membrane electrode is easily oxidized by air, thereby reducing the stability of the battery
Moreover, it can only use a methanol solution with a concentration of less than 5mol / L

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Self-breathing direct methanol fuel cell

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0046] The structure of the self-breathing methanol direct fuel cell is as follows figure 1 shown.

[0047] The supporting board A is a glass fiber reinforced polyester board, the second air-permeable board B is graphite paper with a thickness of 0.8 mm, and the first air-permeable board C is a graphite board with a thickness of 0.8 mm.

[0048] The anode current collector H and the cathode current collector J are metal sheets with a thickness of 0.06 mm.

[0049] The effective work area of ​​membrane electrode I is 2×2.5=5cm 2 .

[0050] The self-breathing direct methanol fuel cell of the present embodiment is subjected to a discharge test. When 10mL of 15M methanol solution is injected into the methanol storage tank, the self-breathing direct methanol fuel cell can operate between 0.3V and 0.4V at a current of 60 mA. Continuous discharge for 60 hours.

Embodiment 2

[0052] Ten self-breathing methanol direct fuel cells described in Example 1 were connected in series to form a stack, and 120mL of 15M methanol solution was used for the discharge test, and the discharge could be continued at 3V~4V for 50 hours at a current of 60mA.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
thicknessaaaaaaaaaa
thicknessaaaaaaaaaa
thicknessaaaaaaaaaa
Login to View More

Abstract

The invention provides a self-breathing direct methanol fuel cell which comprises a methanol storage tank, an anode supporting plate, an anode current collecting plate, a membrane electrode, a cathode current collecting plate and a cathode supporting layer which are successively connected. The self-breathing direct methanol fuel cell is characterized in that a supporting plate and a first ventilation plate are sequentially connected between the methanol storage tank and the anode supporting plate; the supporting plate is provided with a fuel filling port and a gas releasing port, and the surface of the supporting plate in connection with the first ventilation plate is provided with a current field; and the first ventilation plate is provided with a fuel filling port and a gas releasing port, the fuel filling port of the supporting plate is communicated with the fuel filling port of the first ventilation plate, and the gas releasing port of the supporting plate is communicated with the gas releasing port of the first ventilation plate. The cell provided by the invention has the advantages that a carbon dioxide semi-enclosed region is formed so as to prevent external oxygen from entering the cell and prevent an anode from being oxidized, the property of the methanol fuel cell provided by the invention is stable, a methanol solution the concentration of which is more than 5M is utilized, and the discharging time is long.

Description

technical field [0001] The invention relates to the field of methanol fuel cells, in particular to a self-breathing direct methanol fuel cell. Background technique [0002] Direct methanol fuel cell is a kind of proton exchange membrane fuel cell, which directly uses methanol solution or steam methanol as the source of fuel supply, without the need for reforming methanol, gasoline or natural hydrogen to generate hydrogen. Direct methanol fuel cells have broad application prospects in portable electronic devices due to their low operating temperature, high specific energy density, simple structure, and good safety. [0003] Among them, the self-breathing direct methanol fuel cell is considered to be the most marketable fuel cell. It uses methanol solution as fuel and oxygen in the air as oxidant to oxidize methanol at the anode of the membrane electrode to release electrons and carbon dioxide. , the electrons reach the cathode through the proton exchange membrane, react with...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): H01M8/02H01M8/04H01M8/22H01M8/04186H01M8/1011
CPCY02E60/50
Inventor 邢巍廖建辉张玉微严亮李晨阳
Owner CHANGZHOU INST OF ENERGY STORAGE MATERIALS &DEVICES
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products