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Processing method of high-concentration industrial phenolic wastewater

A treatment method and technology for phenolic wastewater, applied in extraction water/sewage treatment, water/sewage multi-stage treatment, water/sludge/sewage treatment, etc., can solve the problems of emulsification, restricting the promotion of phenol-ammonia recovery and extraction process, and pollution , to achieve the effect of less solvent loss

Active Publication Date: 2014-05-21
EAST CHINA ENG SCI & TECH
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Problems solved by technology

However, the traditional extraction process often has a series of problems such as emulsification, pollution, and toxicity due to the improper selection of the extraction agent. The wastewater after extraction often cannot meet the requirements. At the same time, the operating cost is relatively high, and it is difficult to achieve economic benefits. Promotion of Recovery Extraction Process

Method used

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Embodiment

[0022] The phenol-containing wastewater first enters the deacidification tower, and is indirectly heated with 0.5MPa.G saturated steam in the tower to remove the acidic substances CO2 and H2S in the phenol-containing wastewater. The temperature of the phenol water entering the deacidification tower is controlled at 85°C, the temperature of the phenol water exiting the deacidification tower is controlled at 102°C, and the temperature of the gas leaving the top of the deacidification tower is controlled at 45°C. The pressure of phenol water entering the deacidification tower is controlled at 0.5MPa.G, the pressure of phenol water exiting the deacidification tower is controlled at 0.35MPa.G, and the pressure of the gas at the top of the deacidification tower is controlled at 0.004MPa.G.

[0023] Then use diisopropyl ether as the extractant and phenol-containing wastewater in a weight ratio of 9:1 to carry out mixing and separation in the extraction tower to recover the mixed pheno...

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Abstract

The invention provides a processing method of high-concentration industrial phenolic wastewater. According to the processing method of the high-concentration industrial phenolic wastewater, an efficient extracting agent and the phenolic wastewater are fed into an extracting tower to be mixed at a certain ratio, and then the high-purity phenolic wastewater is extracted and pre-processed at a certain temperature through a reverse liquid-liquid contact. The wastewater processed by the processing method provided by the invention can meet the requirement of various water quality indexes of biochemical treatment; the problem due to process current high-concentration phenolic amino wastewater produced via chemical enterprise is solved; the crude phenol and stronger ammonia water which are in a certain economic value can be recovered; and the optimal win-win combination of environment-friendly performance and economic benefit is achieved. The processing method provided by the invention is simple in technical process, continuous, and low in energy consumption; the extracting agent can be recycled; the scale production can be completely achieved; the basic state policy of integral sustainable development on resource, energy and environment is really demonstrated; and good circulation of three benefits is achieved, which means the harmony and unity on society, economy and environment.

Description

technical field [0001] The invention relates to a treatment method for high-concentration industrial phenol-containing wastewater, which is particularly suitable for treating high-concentration phenol-containing wastewater from coal chemical production. Background technique [0002] Phenol-containing wastewater mainly comes from high-temperature coking, medium-low temperature pyrolysis, or fixed-bed coal gasification and other coal chemical production fields. It must be pretreated to recover phenol and ammonia before it can enter the biochemical treatment device for further advanced treatment. [0003] At present, the treatment methods of phenol-containing wastewater are widely used at home and abroad. The process and flow selection of phenol recovery are mainly determined according to the total phenol content in the wastewater. According to the introduction of relevant information and the experience of related process equipment, when the total phenol content in the wastewa...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F9/10C01C1/02C07C37/72C07C37/68C02F1/26
Inventor 安承东吴健
Owner EAST CHINA ENG SCI & TECH
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