High-strength and high-modulus polyvinyl alcohol fiber and melt spinning method of high-strength and high-modulus polyvinyl alcohol fiber
A technology of polyvinyl alcohol fiber and melt spinning, which is applied in the direction of melt spinning, stretch spinning, fiber treatment, etc. It can solve the problems of complex extraction, long production process, high cost, etc., and achieve the effect of simple process
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Embodiment 1
[0039] A high-strength high-modulus polyvinyl alcohol fiber and a melt spinning method thereof, comprising the following steps:
[0040] (1) swelling;
[0041] The raw material is polyvinyl alcohol powder or pellets with a degree of polymerization of 800 and a degree of alcoholysis of 60%. Water is used as a plasticizer, and after being fully mixed, it is swelled at 20°C for 4 hours; the weight ratio of polyvinyl alcohol, water and glycerin is 1: 0.3∶0.05;
[0042] (2) Melt spinning;
[0043] Add the swollen polyvinyl alcohol into the twin-screw extruder, fully melt it, pass through the spinning assembly and spray it out from the spinneret with a hole diameter of 0.1mm, and the melt stream is cooled by side blowing to obtain the primary polyvinyl alcohol fiber The temperature in each zone of the screw is: 70°C in the feed section, 90°C in the compression section and 80°C in the metering section, 90°C in the spinning assembly, 80°C in the spinneret, and a spinning speed of 10...
Embodiment 2
[0047] A high-strength high-modulus polyvinyl alcohol fiber and a melt spinning method thereof, comprising the following steps:
[0048] (1) swelling;
[0049] The raw material is polyvinyl alcohol powder or pellets with a degree of polymerization of 2600 and a degree of alcoholysis of 99%. Water is used as a plasticizer. The weight ratio is 1:1.5:0.2;
[0050] (2) Melt spinning;
[0051] The swollen polyvinyl alcohol is added to the steam-tight twin-screw extruder, and the combination of the twin-screw screw elements of the steam-tight twin-screw extruder is sequentially the screw element I, the screw element II and the screw element III. Two cycles, and the threaded element I is connected after the cycle; the main technical parameters of the threaded element of the steam-tight twin-screw extruder are: in the threaded element I, the screw root diameter D 01 = 15mm, screw groove depth h 1 =15mm, thread pitch S 1 =10mm, flight width B 1 = 10mm, 0.3D 01 =h 1 =0.6D 01 , ...
Embodiment 3
[0056] A high-strength high-modulus polyvinyl alcohol fiber and a melt spinning method thereof, comprising the following steps:
[0057] (1) swelling;
[0058] The raw material is polyvinyl alcohol powder or pellets with a degree of polymerization of 1700 and a degree of alcoholysis of 99%. Water is used as a plasticizer. After being fully mixed, it is swelled at 45°C for 2 hours; the weight ratio of polyvinyl alcohol, water and pentaerythritol is 1: 1:0.11;
[0059] (2) Melt spinning;
[0060] Add the swollen polyvinyl alcohol into the twin-screw extruder, fully melt it, pass through the spinning assembly and spray it out from the spinneret with a hole diameter of 0.5mm, and the melt stream is cooled by side blowing to obtain the primary polyvinyl alcohol fiber The temperature of each zone of the screw is: 80°C in the feed section, 120°C in the compression section, and 150°C in the metering section, the temperature of the spinning assembly is 150°C, the temperature of the s...
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