Flocculating agent and preparation method thereof
A flocculant and initiator technology, used in the field of flocculants and their preparation, can solve the problems of reducing the hydrodynamic volume of organic polymer flocculants, changing the structure of polymer chains, affecting the flocculation effect, etc., and achieves excellent flocculation effect, enhanced Anti-salt ability, improve the effect of flocculation
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[0021] The embodiment of the present invention discloses a preparation method of a flocculant, comprising the following steps:
[0022] a) dissolving acrylamide, acrylic acid and methacryloxyethyl dimethyl benzyl ammonium chloride in water to obtain a mixed solution;
[0023] The molar ratio of the acrylic acid to methacryloxyethyl dimethyl benzyl ammonium chloride is 1: 0.5~1.5;
[0024] b) In an inert gas environment, the mixed solution in step a) undergoes a polymerization reaction under the action of an initiator to obtain a flocculant.
[0025] The present invention uses acrylamide, acrylic acid and methacryloxyethyl dimethyl benzyl ammonium chloride as raw materials, and in step a), acrylamide, acrylic acid and methacryloxyethyl dimethyl benzyl chloride are The ammonium is dissolved in water to obtain a mixed solution; the molar ratio of the acrylic acid to methacryloxyethyl dimethyl benzyl ammonium chloride is 1:0.5-1.5, preferably 1:1. The ratio of the total amount o...
Embodiment 1
[0035] Into a four-neck reaction flask with condensed water, mechanical stirrer, nitrogen inlet and dropping funnel, add 0.18mol acrylamide, 0.01mol acrylic acid and 0.01mol methacryloxyethyl dimethyl benzyl ammonium chloride Dissolve in 303.62mL deionized water to obtain a mixed solution. NaOH solution with a mass concentration of 20 wt% was added dropwise to the mixed solution to adjust the pH value of the mixed solution to 8.0.
[0036] Nitrogen gas was blown into the mixed solution for 30 minutes, the temperature was raised to 30° C., 0.0002 mol of azobisisobutylimidazoline hydrochloride was added, and the reaction was carried out for 24 hours to obtain the product. The product is dialyzed and precipitated with acetone to obtain a flocculant.
[0037] The flocculation performance test was carried out on the obtained flocculant, and the results showed that:
[0038] The montmorillonite suspension with a mass fraction of 1% has a turbidity of 2000, adding 150ppm flocculant...
Embodiment 2
[0043] Into a four-neck reaction flask with condensed water, mechanical stirrer, nitrogen inlet and dropping funnel, add 0.038mol acrylamide, 0.001mol acrylic acid and 0.001mol methacryloxyethyl dimethyl benzyl ammonium chloride Dissolve in 97.58mL deionized water to obtain a mixed solution. NaOH solution with a mass concentration of 20 wt% was added dropwise to the mixed solution to adjust the pH value of the mixed solution to 7.0.
[0044] Nitrogen gas was blown into the mixed solution for 30 minutes, the temperature was raised to 50° C., 0.00002 mol of azobisisobutylimidazoline hydrochloride was added, and the reaction was carried out for 12 hours to obtain the product. The product is dialyzed and precipitated with acetone to obtain a flocculant.
[0045] The flocculation performance test was carried out on the obtained flocculant, and the results showed that:
[0046] The montmorillonite suspension with a mass fraction of 1% has a turbidity of 2000, adding 150ppm flocculan...
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