Mg-Al-Ti three-layer composite brick and preparation method thereof

A layer composite, magnesium-aluminum technology, applied in the field of magnesium-aluminum-titanium three-layer composite brick and its preparation, can solve the problems of increased heat dissipation of the kiln shell, brick drop, and increased heat consumption of clinker, etc., to prolong the service life of the equipment , Good refractory heat insulation effect, energy saving effect

Inactive Publication Date: 2012-08-01
SUZHOU LOW CARBON ENERGY CONSERVATION TECH
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Most of the existing refractory bricks and heat insulation bricks are made of a single material. When using them, bricks with various properties need to be used together. If they are used on relatively fixed equipment, such as tunnel kilns and downdraft kilns, they can meet the requirements. , but on some relatively moving equipment, such as a rotary kiln, it is difficult to meet the requirements when used together
Some manufacturers and research units have conducted research and research on this, and have introduced some composite bricks that combine heavy materials and light materials. However, due to the low structural strength of the light parts, they cannot meet the requirements for use, and the The light part is easy to react due to material problems, which affects product performance and use effect, so it has not been widely promoted, and heavy bricks are still the main ones
[0003] Taking the 10,000t / d rotary kiln of Conch Group as an example, spinel bricks are used in the front transition zone, and magnesia-chrome bricks are used in the firing zone. Due to the large thermal conductivity of spinel bricks in the front transition zone and magnesia-chrome bricks in the firing zone (≥ 2.7W / m·K), so that the temperature of the outer wall of the kiln shell is relatively high (about 380°C, and it can reach 420°C at high temperature), which will increase the heat dissipation of the kiln shell on the one hand, thereby increasing the heat consumption of clinker. It will cause an increase in the unit cost of clinker; on the other hand, it is very easy to cause the cylinder to expand due to heat, resulting in an increase in the temperature of the supporting wheel in the middle of the kiln, especially in the later period of use or in summer, which will bring great hidden dangers to the normal operation of the equipment.
The overheating of the cylinder increases the damage probability of mechanical equipment and accelerates the deformation of the cylinder, and the deformation of the cylinder accelerates the mechanical damage of the inner lining. The result is brick falling and kiln shutdown, which affects the operation rate of the cement rotary kiln

Method used

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  • Mg-Al-Ti three-layer composite brick and preparation method thereof
  • Mg-Al-Ti three-layer composite brick and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] Such as figure 1 As shown, the magnesium-aluminum-titanium three-layer composite brick in this embodiment includes a heavy working layer 1 , a light heat insulating layer 3 , and a transition layer 2 between the heavy working layer 1 and the light heat insulating layer 3 .

[0023] in:

[0024] The particle size distribution and mass percentage of the raw materials used in the heavy working layer 1 are: fused magnesia with a particle size larger than 1mm: 33.6%; fused spinel with a particle size larger than 1mm: 1.4%; particle size smaller than 1mm And greater than 325 mesh fused magnesia: 29%; particle size not greater than 325 mesh α-Al 2 o 3 Micropowder: 6%; fused magnesium powder with a particle size of 325 mesh: 24.4%; titanium dioxide with a particle size of 325 mesh: 5.6%. The binding agent adopted during material preparation is magnesium sulfate solution, and its weight is 5% of the weight of the heavy working layer.

[0025] The particle size distribution a...

Embodiment 2

[0034] Such as figure 1 As shown, the magnesium-aluminum-titanium three-layer composite brick in this embodiment includes a heavy working layer 1 , a light heat insulating layer 3 , and a transition layer 2 between the heavy working layer 1 and the light heat insulating layer 3 .

[0035] in:

[0036] The particle size distribution and mass percentage of the raw materials used in the heavy working layer 1 are as follows: sintered magnesia with a particle size larger than 1mm: 20%; sintered spinel with a particle size larger than 1mm: 25%; 325 mesh sintered spinel: 15%; sintered magnesia with a particle size of less than 1mm and larger than 325 mesh: 20%; sintered magnesium powder with a particle size of 325 mesh: 18.4%; high titanium slag with a particle size of 325 mesh: 1.6%. The binding agent adopted during material preparation is magnesium sulfate solution, and its weight is 2% of the weight of the heavy working layer.

[0037] The particle size distribution and mass per...

Embodiment 3

[0046] Such as figure 1 As shown, the magnesium-aluminum-titanium three-layer composite brick in this embodiment includes a heavy working layer 1 , a light heat insulating layer 3 , and a transition layer 2 between the heavy working layer 1 and the light heat insulating layer 3 .

[0047] in:

[0048] The particle size distribution and mass percentage of the raw materials used in the heavy working layer 1 are as follows: sintered magnesia with a particle size greater than 1mm: 10%; fused spinel with a particle size greater than 1mm: 28%; Fused spinel larger than 325 mesh: 5%; sintered magnesia with a particle size of less than 1mm and larger than 325 mesh: 22%; sintered magnesium powder with a particle size of 325 mesh: 5%; fused spinel with a particle size of 325 mesh: 13%; titanium yellow powder with a particle size of 325 mesh: 17%. The binding agent that adopts when preparing materials is yellow dextrin solution, and its weight is 2% of heavy working layer weight.

[00...

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Abstract

The invention provides a Mg-Al-Ti three-layer composite brick with good wear resistance, high fire resistance, high structural strength and good heat-insulating performance and a preparation method thereof, so that the composite brick has both fire resistance and heat insulating function and the energy-saving effect of a rotary kiln is improved. The Mg-Al-Ti three-layer composite brick comprises a heavy-weight working layer made of Mg-Al-Ti material, a light-weight heat insulating layer made of electric smelting hollow sphere, and a transitional layer arranged between the heavy-weight working layer and the light-weight heat insulating layer and made of spinel, magnesium aluminum chromium or magnesium aluminum titanium or magnesium spinel zirconium. Since the transitional layer is introduced into the Mg-Al-Ti three-layer composite brick, the reaction between the heavy-weight working layer and the light-weight heat insulating layer is avoided and the product has good fire-resistance and heat-insulating effect under the condition that the service life of the materials is not reduced, the functions of lowering energy consumption, reducing material consumption and decreasing the fire-resistance material consumption of the rotary kiln are achieved, and the service life of equipment is prolonged effectively.

Description

technical field [0001] The invention belongs to the technical field of refractory materials, and in particular relates to a magnesium-aluminum-titanium three-layer composite brick and a preparation method thereof. Background technique [0002] With the continuous emergence of new technologies for cement production, the main equipment of cement production is developing in the direction of large-scale, increasing production, improving quality, saving energy, reducing consumption, and reducing costs have become the key to increasing efficiency in production management. Most of the existing refractory bricks and heat insulation bricks are made of a single material. When using them, bricks with various properties need to be used together. If they are used on relatively fixed equipment, such as tunnel kilns and downdraft kilns, they can meet the requirements. , but on some relatively moving equipment, such as a rotary kiln, it is difficult to meet the requirements when used togeth...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B35/66
Inventor 王家邦
Owner SUZHOU LOW CARBON ENERGY CONSERVATION TECH
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