Catalyst for catalyzing CO oxidation in smoke of cigarettes as well as preparation method and application of catalyst
A technology for catalyzing flue gas and catalysts, which can be used in metal/metal oxide/metal hydroxide catalysts, physical/chemical process catalysts, chemical instruments and methods, etc., and can solve the problems of high cost, low reserves, and harsh preparation conditions. , to achieve the effect of improving the quality of absorbing taste, improving the quality of absorbing taste and simple preparation process
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Embodiment 1
[0016] Measure 400 milliliters of distilled water into the beaker, and weigh 1.2 grams of La according to the stoichiometric ratio 2 o 3 and 3 grams of sodium carbonate precipitant were added to distilled water, heated to 40°C while stirring, and stirred for 60 minutes (including the heating process). Measure 22.5 milliliters of zinc nitrate solution (1mol / L), 7.5 milliliters of ferric nitrate solution (1mol / L) and 15 milliliters of manganese nitrate solution (1mol / L) and fully mix together, after 30 minutes, mix the above three components The mixture was added dropwise to sodium carbonate and La 2 o 3 in the mixed solution. Then add aluminum latex (aluminum latex prepared from 15 ml of aluminum nitrate), adjust pH=8, and react at 40° C. for 6 hours. Wash again 5 times with distilled water. Filter under reduced pressure, dry at 140°C for 6 hours, and roast at 600°C for 4h to obtain ZnO-Fe 2 o 3 -La 2 o 3 -MnO 2 -Al 2 o 3 = 3:1:1:2:2 catalyst.
Embodiment 2~5
[0018] Preparation method is identical with example 1, and manganese nitrate is changed into copper nitrate, nickel nitrate, magnesium nitrate and cobalt nitrate respectively. ZnO-Fe was prepared separately 2 o 3 -La 2 o 3 -CuO-Al 2 o 3 =3:1:1:2:2,
[0019] ZnO-Fe 2 o 3 -La 2 o 3 -NiO-Al 2 o 3 =3:1:1:2:2,
[0020] ZnO-Fe 2 o 3 -La 2 o 3 -MgO-Al 2 o 3 =3:1:1:2:2,
[0021] ZnO-Fe 2 o 3 -La 2 o 3 -CoO 2 -Al 2 o 3 =3:1:1:2:2. catalyst. The above-mentioned catalyst was added to shredded tobacco, and each cigarette contained 30 mg of the catalyst, and these sample cigarettes containing the catalyst were analyzed by a smoking machine to determine the CO content in the cigarette smoke.
[0022] The test result of table one embodiment in cigarette
[0023] sample example
Embodiment 6
[0025] Measure 400 milliliters of distilled water into the beaker, and weigh 1.2 grams of La according to the stoichiometric ratio 2 o 3 and 3 grams of sodium carbonate precipitant were added to distilled water, heated to 40°C while stirring, and stirred for 120 minutes (including the heating process). Measure 22.5 milliliters of zinc nitrate solution (1mol / L), 7.5 milliliters of ferric nitrate solution (1mol / L) and 7.5 milliliters of copper nitrate solution (1mol / L) and fully stir, evenly mix together, after 30 minutes, above-mentioned three The mixture of the two components was added dropwise to sodium carbonate and La 2 o 3 in the mixed solution. Then add aluminum latex (aluminum latex prepared from 22.5 ml of aluminum nitrate), adjust pH=9, and react at 40° C. for 3 hours. Wash again 5 times with distilled water. Filter under reduced pressure, dry at 120°C for 3 hours, and roast at 300°C for 2 hours to obtain ZnO-Fe 2 o 3 -La 2 o 3-CuO-Al 2 o 3 = 3:1:1:1:3 catal...
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