CdS single crystal nanowire solar battery and preparation method of the same
A technology of solar cells and single crystal nanometers, applied in the field of solar cells, can solve the problems of low photoelectron injection efficiency and transmission and collection efficiency, and achieve the effects of being conducive to commercial production and application, convenient preparation, and high injection efficiency
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Embodiment 1
[0037] Mix 25mL of deionized water, 2.5mL of 0.12M / L cadmium chloride (CdCl 2 ), 10mL of 0.20M / L ammonium chloride (NH 4 Cl), 15mL of 2M / L ammonia water (NH 3 ·H 2 (2) and 2.5mL of 0.6M / L thiourea were added to the same beaker, the FTO glass sheet was vertically submerged into the reaction solution, and the pH value of the whole reaction system was controlled between 10 and 11, heated in a water bath, and the temperature was constant at 80 ℃. After reacting for 15 minutes, the FTO glass piece was taken out, washed with deionized water, dried under nitrogen flow, annealed at 400°C for 1 hour, and cooled in a furnace. The seed layer is prepared.
[0038] Weigh 1.25 g of Cd(NO 3 ) 2 4H 2 O and 0.925 grams of thiourea were dissolved in 40 mL of ethylenediamine solution, and magnetically stirred for about 15 min until the reactant was completely dissolved; the FTO conductive glass with the CdS seed layer was put into a hydrothermal reaction kettle with the above mixed solution...
Embodiment 2
[0047] Mix 25 mL of deionized water, 625 μL of 0.12M / L cadmium chloride (CdCl 2 ), 10mL of 0.20M / L ammonium chloride (NH 4 Cl), 15mL of 2M / L ammonia water (NH 3 ·H 2 (2) and 625 μL of 0.6M / L thiourea were added into the same beaker, the reaction time was 40min, and all other steps were completely the same as in Example 1.
[0048] The particle size of the seed layer prepared under this condition becomes smaller, about 20nm, and the filling factor of the prepared battery is 1.5 times that of Example 1, which can reach 61%, indicating that the utilization efficiency of the entire battery system for photoelectrons is very high .
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