Collector for bipolar lithium ion secondary battery
A secondary battery and current collector technology, applied in secondary batteries, secondary battery manufacturing, large flat batteries/batteries, etc., can solve the problem of reduced output power, unfavorable battery space, reduced battery output power density, and energy density, etc. problems, to achieve the effect of preventing penetration and absorption
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Embodiment 1
[0105]
[0106] As a 1st electroconductive layer, the electroconductive resin film (film thickness: 25 micrometers) which mixed 10 mass % of ketjen blacks to 100 mass % of polyimide (PI) was prepared.
[0107] On the other hand, 10% by mass of Ketjen Black was mixed with 100% by mass of ethylene-vinyl alcohol copolymer (ethylene composition: 38 mol%) (EVOH) just melted, and a conductive resin film (film thickness: 25 μm), as the second conductive layer.
[0108] The first conductive layer and the second conductive layer prepared and fabricated as described above were stacked and heat-sealed at 160° C. for 10 minutes to fabricate a current collector for a bipolar lithium ion secondary battery having a two-layer structure.
[0109]
[0110] LiMn mixed as positive electrode active material 2 o 4 85% by mass, 5% by mass of acetylene black as a conductive additive, 10% by mass of polyvinylidene fluoride (PVDF) as a binder, and an appropriate amount of N-methyl-2-pyrrolidone ...
Embodiment 2
[0121] A bipolar secondary battery was produced in the same manner as in Example 1 above, except that the blending amount of Ketjen Black was 5% by mass relative to 100% by mass of EVOH when producing the second conductive layer.
Embodiment 3
[0123] As the first conductive layer, a material with a film thickness of 12.5 μm was used, and the second conductive layer was produced so as to have a film thickness of 37.5 μm. By the same method as in the above-mentioned Example 1, a Bipolar secondary battery.
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