Biological desulphurization processing reactor, biological desulphurization processing system, and processing method
A biological desulfurization and reactor technology, applied in the field of environmental engineering, can solve the problems of increasing the difficulty of separation and purification of elemental sulfur, short solid residence time, blockage of elemental sulfur, etc., to prolong the solid residence time, lower operation and maintenance costs, and prevent loss Effect
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Embodiment 1
[0079] Example 1: Simulation of sulfide-containing wastewater
[0080] 1) Immobilized Thiobacillus, with Na 2 S 2 o 3 5~10g / L, KNO 3 5~10g / L, NaHCO 3 2g / L, KH 2 PO 4 0.1g / L culture medium at 30°C for 14 days, mix the bacterial solution with the immobilized carrier, continue to culture in the above method for 10-14 days, replace the medium every 3-4 days;
[0081] 2) Start the reactor, place the activated immobilized Thiobacillus in the reactor, and control the initial load of the reactor at 1-3kgS / (m 3 d), the load is increased by 2kgS / (m every 3 days 3 d).
[0082] 3) The temperature of the influent water is 30-35°C, and the oxidation-reduction potential value (redox potential) is controlled at -150--100mV. When the potential value is higher than the set value, the water intake will be increased and the air flow will be reduced.
[0083] Below are the parameters and the results of Example 1:
[0084] Simulated wastewater (mg / L): Na 2 S100~500, NaHCO 3 20. K 2 HP...
Embodiment 2
[0090] Embodiment 2: the absorbing liquid that gas removes hydrogen sulfide
[0091] Simulated hydrogen sulfide-containing gas (v / v): 4%H 2 S, 96%N 2
[0092] 1) With pH10~11, 0.1M NaHCO 3 / Na 2 CO 3 It is the absorption liquid, after being absorbed by the packed gas-liquid exchange tower, the concentration of sulfide is 100mmolS / L absorption liquid, the pH is 7.5-8.0, and the sulfide content is 60-100mmol. The absorption liquid is pumped to the mixer and enters the reaction device.
[0093] 2) According to the concentration of sulfide in the influent, adjust the hydraulic retention time of the reactor to keep the load of the biological desulfurization device at 12kgS / (m 3 About d), the sulfide removal rate of the treated absorption liquid is >98%, the elemental sulfur generation rate is >80%, and the pH value of the treated absorption liquid rises to 10, which can be used again for the absorption and purification of hydrogen sulfide gas.
[0094] The sulfide-containing...
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