Self-crosslinking organosilicone heat-resistant coating

A heat-resistant coating, silicone technology, applied in the coating and other directions, can solve the problems of low mechanical strength, poor self-drying performance, reduced silicone content, etc., and achieve the effect of excellent physical and chemical properties and good drying performance.

Active Publication Date: 2013-04-10
西安经建油漆有限责任公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] The current silicone heat-resistant coatings have poor self-drying properties. Generally, one-component silicone coatings must be baked and cured at a temperature of 150°C. The self-drying silicone coatings on the market either rely on the volatilization of solvents to form films. The mechanical strength of the coating is very low before heat resistance, and the protective performance is very poor, either by introducing reactive organic groups, such as hydroxyl groups, epoxy groups, etc., to achieve the purpose of curing through the crosslinking reaction of active organic groups. Although the coating has good mechanical strength and protective properties, the content of organic silicon is greatly reduced, and the heat resistance of the coating is limited.

Method used

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  • Self-crosslinking organosilicone heat-resistant coating

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] The synthetic process step of modified silicone resin of the present invention is as follows:

[0017] 1) Synthesis of acrylic acid prepolymer: take 13kg of methyl methacrylate, 20kg of styrene, 8kg of butyl acrylate, 3kg of acrylic acid, 1.3kg of benzoyl peroxide, and 45kg of xylene; Add it into the reaction kettle, raise the temperature to reflux temperature (138-140°C), mix the mixture of acrylic acid monomer, methyl methacrylate, styrene, butyl acrylate and benzoyl peroxide for 2 hours (at 2- 2.5 hours) dropwise addition; reflux for 2 hours, then cool down; when the temperature drops to 80°C, discharge the material for later use;

[0018] 2) Synthesis of organosilicon intermediates: Take 15kg of phenyltrichlorosilane, 8kg of dimethyldichlorosilane, 35kg of toluene, 30kg of ethanol, and 12kg of deionized water; mix deionized water with 2 / 3 toluene is added to the hydrolysis kettle, and the mixture of phenyltrichlorosilane, dimethyldichlorosilane and the remaining 1 / ...

Embodiment 2

[0021] Synthesis of modified silicone resin of the present invention:

[0022] 1) Synthesis of acrylic acid prepolymer: Take 15kg of methyl methacrylate, 25kg of styrene, 10kg of butyl acrylate, 5kg of acrylic acid, 1.5kg of benzoyl peroxide, and 50kg of xylene; add xylene In the reaction kettle, heat up to the reflux temperature (138-140°C), and add the mixture of acrylic acid monomer, methyl methacrylate, styrene, butyl acrylate and benzoyl peroxide dropwise in 2.5 hours; reflux Keep warm for 2 hours, then cool down; when the temperature drops to 80°C, discharge the material for later use;

[0023]2) Synthesis of organosilicon intermediates: Take 20kg of phenyltrichlorosilane, 10kg of dimethyldichlorosilane, 40kg of toluene, 35kg of ethanol, and 15kg of deionized water; mix deionized water with Add 2 / 3 toluene into the hydrolysis kettle, drop the mixture of phenyltrichlorosilane, dimethyldichlorosilane and the remaining 1 / 3 toluene from the high position tank, control the f...

Embodiment 3

[0026] Synthesis of modified silicone resin of the present invention:

[0027] 1) Synthesis of acrylic acid prepolymer: Take 12kg of methyl methacrylate, 15kg of styrene, 5kg of butyl acrylate, 1kg of acrylic acid, 1kg of benzoyl peroxide, and 40kg of xylene; add xylene Into the reaction kettle, heat up to the reflux temperature (138-140°C), add the mixture of acrylic acid monomer, methyl methacrylate, styrene, butyl acrylate and benzoyl peroxide dropwise in 2.2 hours; reflux Keep warm for 2 hours, then cool down; when the temperature drops to 80°C, discharge the material for later use;

[0028] 2) Synthesis of organosilicon intermediates: take 10kg of phenyltrichlorosilane, 5kg of dimethyldichlorosilane, 20kg of toluene, 20kg of ethanol, and 5kg of deionized water; mix deionized water with 2 / 3 toluene is added to the hydrolysis kettle, and the mixture of 1-phenyltrichlorosilane, dimethyldichlorosilane and the remaining 1 / 3 toluene is added dropwise from the high position tan...

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Abstract

The invention relates to a self-crosslinking organosilicone heat-resistant coating capable of reaching good drying properties and excellent physical and chemical properties through a self-crosslinking reaction. The self-crosslinking organosilicone heat-resistant coating is characterized in that the coating is prepared from the following raw materials in parts by weight: 50-60 parts of modified organosilicone resins with a concentration not less than 60%, 0.3 part of dispersant BYK, 0.4 part of organic bentonite, 10-15 parts of pigment, 5-10 parts of mica powder with a particle size of 350-450meshes, 5-10 parts of precipitate barium sulfate with a particle size of 350-450 meshes, 5-10 parts of talc powder with a particle size of 350-450 meshes and 10-20 parts of xylene; and the coating can achieve good drying properties and excellent physical and chemical properties through a self-crosslinking reaction in a 25 DEG C environment. Through the coating, the shortcomings of the existing one-component organosilicone products are solved, the coating has good heat resistance, and simultaneously the coating layer formed by the coating has excellent mechanical strength and protective properties. The coating provided by the invention is adaptable to the decorative protection of large-sized heat-resistant components, the components coated by the coating can withstand the temperature of 450 DEG C for a long term and can withstand long-term UV (ultraviolet) exposure, and the coating layer is not damaged.

Description

technical field [0001] The invention relates to a coating, in particular to a self-crosslinking silicone heat-resistant coating which can achieve good drying performance and excellent physical and chemical properties through self-crosslinking reaction. Background technique [0002] The current silicone heat-resistant coatings have poor self-drying properties. Generally, one-component silicone coatings must be baked and cured at a temperature of 150°C. The self-drying silicone coatings on the market either rely on the volatilization of solvents to form films. The mechanical strength of the coating is very low before heat resistance, and the protective performance is very poor, either by introducing reactive organic groups, such as hydroxyl groups, epoxy groups, etc., to achieve the purpose of curing through the crosslinking reaction of active organic groups. Although the coating has good mechanical strength and protective properties, the content of organic silicon is greatly...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08G77/06C09D183/04
Inventor 张海信姚江柳宫密芳赵绍芬
Owner 西安经建油漆有限责任公司
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