Method for preparing waterproof adhesive for corrugated paper production
An adhesive and corrugated paper technology, applied in the direction of adhesives, starch-derived adhesives, adhesive types, etc., can solve the problems of slow drying speed and low water resistance of adhesives, and achieve improved water resistance, good fast drying characteristics, Reduce the effect of damage
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Embodiment 1
[0015] Embodiment 1: the synthesis of starch-isopropenyl acetate cross-linked graft copolymer, take starch as raw material, after being mixed with the starch emulsion that mass percent concentration is 40%, take acetic acid as catalyst, take ammonium persulfate as initiator , under the condition of pH=3, slowly add 85% isopropenyl acetate monomer of starch quality dropwise to carry out graft copolymerization reaction, graft copolymerization reaction temperature is 60 ℃, graft copolymerization reaction time is 6 hours, in After the graft copolymerization reaction for 2 hours, N, N'-methylene bisacrylamide with a mass concentration of 0.2% of the starch and a mass concentration of 1% was added as a crosslinking agent to carry out the crosslinking reaction, and the addition and reaction were all carried out under stirring. The reaction product is starch-isopropenyl acetate cross-linked graft copolymer.
[0016] Using the synthesized starch-isopropenyl acetate cross-linked graft c...
Embodiment 2
[0019] The synthesis of starch-isopropenyl acetate cross-linked graft copolymer, with starch as raw material, after being mixed with the starch emulsion that mass percent concentration is 45%, with acetic acid as catalyst, with ammonium persulfate as initiator, at pH= Under the condition of 4, slowly add 90% isopropenyl acetate monomer of starch quality dropwise to carry out graft copolymerization reaction, graft copolymerization reaction temperature is 70 ℃, graft copolymerization reaction time is 5 hours, in graft copolymerization reaction After 2 hours, add N, N'-methylenebisacrylamide with a starch mass of 0.3% and a mass concentration of 1.5% as a crosslinking agent for crosslinking reaction. The addition and reaction are all carried out under stirring, and the reaction product is starch - Isopropenyl acetate cross-linked graft copolymer.
[0020] Using the synthesized starch-isopropenyl acetate cross-linked graft copolymer as the main raw material, add caustic soda with ...
Embodiment 3
[0023] The synthesis of starch-isopropenyl acetate cross-linked graft copolymer, with starch as raw material, after being mixed with the starch emulsion that mass percent concentration is 50%, with acetic acid as catalyst, with ammonium persulfate as initiator, at pH= Under the condition of 5, slowly add 95% isopropenyl acetate monomer of starch quality dropwise to carry out graft copolymerization reaction, graft copolymerization reaction temperature is 80 ℃, graft copolymerization reaction time is 4 hours, in graft copolymerization reaction After 2 hours, add N, N'-methylenebisacrylamide with a mass concentration of 0.5% of starch and a mass concentration of 2% as a crosslinking agent for crosslinking reaction. The addition and reaction are all carried out under stirring, and the reaction product is starch - Isopropenyl acetate cross-linked graft copolymer.
[0024] Using the synthesized starch-isopropenyl acetate cross-linked graft copolymer as the main raw material, add cau...
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