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High-efficiency nickel-molybdenum catalyst

A catalyst and high-efficiency technology, applied in the direction of physical/chemical process catalysts, metal/metal oxide/metal hydroxide catalysts, chemical instruments and methods, etc., can solve the problem of increased difficulty in refining technology, reduced catalyst anti-coking ability, It is not easy to solve problems such as deep denitrification process, so as to achieve the effect of improving anti-coking ability, improving refining efficiency and improving catalytic effect

Inactive Publication Date: 2011-01-19
姚光纯
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the catalysts used in oil refining mainly include unit catalysts such as platinum catalysts and nickel catalysts. However, as the content of impurities in crude oil increases, the quality of oil decreases, and the technical difficulty of oil refining increases. The existing catalysts are prone to aging and caking during use. , it is not easy to form a deep denitrification process, which reduces the anti-coking ability of the catalyst and leads to a decrease in the catalytic effect of the catalyst

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0007] Example 1, the high-efficiency nickel-molybdenum catalyst is prepared according to the following method: firstly, honeycomb ceramic carriers of various specifications are produced according to the existing honeycomb ceramic preparation process, and the honeycomb ceramic carrier has a pore size of 3 × 3mm The mesh square honeycomb holes, and then the honeycomb ceramic carrier is impregnated with nickel oxide (NiO) and molybdenum trioxide (Mo 2 o 3 ) in the catalytic membrane solution for 5-8 minutes, and then bake the soaked honeycomb ceramic carrier at a high temperature of 500-600°C for 1.5 hours, so that a layer with an average thickness of 0.35mm is formed on the surface of the pores of the honeycomb ceramic carrier The catalytic film is composed of nickel oxide and molybdenum trioxide, the content of nickel oxide in the catalytic film is 0.6% of the weight of the high-efficiency nickel-molybdenum catalyst, and the content of dimolybdenum trioxide is 2% of the weight...

Embodiment 2

[0008] Embodiment 2, the high-efficiency nickel-molybdenum catalyst described in this embodiment 2 is prepared by the following method, and the cuboid honeycomb ceramic carrier is produced first according to the preparation technology of existing honeycomb ceramic, and there is aperture in this honeycomb ceramic carrier It is 4×4mm mesh square honeycomb holes, and then soak the honeycomb ceramic carrier in the catalytic membrane solution for 5-6 minutes, and then bake the soaked honeycomb ceramic carrier at a high temperature of 500-600°C for 1.2 hours , the surface of the hole in the honeycomb ceramic carrier forms a catalytic membrane with a thickness of 0.7mm, the catalytic membrane is made up of nickel oxide and molybdenum trioxide, and the content of nickel oxide in the catalytic membrane is 2% of the weight of the high-efficiency nickel-molybdenum catalyst The content of dimolybdenum trioxide is 5.5% of the weight of the high-efficiency nickel-molybdenum catalyst, that is...

Embodiment 3

[0009] Embodiment 3, the high-efficiency nickel-molybdenum catalyst described in this embodiment 3 is prepared by the following method. First, a rectangular parallelepiped honeycomb ceramic carrier is produced according to the existing preparation process of honeycomb ceramics. The honeycomb ceramic carrier has the largest It is formed by immersing the honeycomb ceramic carrier in the catalyst solution for 6-8 minutes, and then baking the soaked honeycomb ceramic carrier at a high temperature of 500-600°C for 1.8 hours. , a catalyst film with a thickness of 1.2 mm is formed on the surface of the holes in the honeycomb ceramic carrier, the catalytic film is composed of nickel oxide and molybdenum trioxide, and the content of nickel oxide in the catalytic film is 1% of the weight of the high-efficiency nickel-molybdenum catalyst The content of dimolybdenum trioxide is 3% of the weight of the high-efficiency nickel-molybdenum catalyst, that is, the weight ratio of nickel oxide to ...

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Abstract

The invention discloses a high-efficiency nickel-molybdenum catalyst which consists of a honeycomb ceramic carrier and a catalytic film. In the invention, the honeycomb ceramic carrier is soaked in a catalytic film solution containing nickel oxide and molybdenum sesquioxide for 5-10 minutes, and then the soaked honeycomb ceramic carrier is roasted at a high temperature of 500-600 DEG C to ensure that a catalytic film consisting of the nickel oxide and the molybdenum sesquioxide is formed on the hole surface of the honeycomb ceramic carrier, wherein the content of the nickel oxide in the catalytic film is 0.5-2 percent of the weight of the high-efficiency nickel-molybdenum catalyst, and the content of the molybdenum sesquioxide is 2-8 percent by weight of the weight of the high-efficiency nickel-molybdenum catalyst. The invention is beneficial to the quickening of the advance removal of sulphur, nitrogen, heavy metals, and the like in crude oil before the oil enters the catalyst bed layer, thereby enhancing the absorption of ammonia, improving the denitration rate and achieving the purpose of deeply denitrifying of the crude oil. Compared with the traditional catalysts, the invention has the advantages of high strength, large specific surface area, difficult aging and hardening, improves the catalytic effect and is beneficial to the improving of the running temperature range of oil refining, the reducing of the oil refining running treatment pressure drop, the enhancing of the oil refining efficiency and the decreasing of the oil refining cost.

Description

technical field [0001] The invention relates to a catalyst, in particular to a high-efficiency nickel-molybdenum catalyst. Background technique [0002] As we all know, catalysts play an extremely important role in the modern chemical industry. Almost half of chemical products use catalysts in the production process to speed up chemical reactions, improve reaction efficiency and obtain products of different qualities. For example, when nitrogen and hydrogen are used to synthesize ammonia, catalysts with iron as the main component are often used. Vanadium pentoxide is often used as a catalyst in the production of sulfuric acid. Platinum catalysts are often used in the purification of motor vehicle exhaust. Different catalysts can be used in oil refining. Gasoline, kerosene, etc. of different qualities. At present, the catalysts used in oil refining mainly include unit catalysts such as platinum catalysts and nickel catalysts. However, as the content of impurities in crude oi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J23/883B01J35/04
Inventor 姚光纯
Owner 姚光纯
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