Environment-friendly polyurethane adhesive used for bonding granulated cork and preparation method thereof
A technology of polyurethane adhesives and cork particles, applied in the direction of polyurea/polyurethane adhesives, adhesive types, non-polymer adhesive additives, etc., can solve problems such as irritating odor, harmful to human health, etc., and achieve high-quality products The effect of excellent performance and shortened mold opening time
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Embodiment 1
[0016] Add 15 grams of polyether polyol DL-2000 (2-functionality, molecular weight 2000) and 15 grams of polyether polyol DL-3000 (2-functionality, molecular weight 3000) into a three-necked bottle at room temperature, and raise it to 80°C- Stir at 100°C, vacuumize, dehydrate and degas until the moisture is qualified (≤0.05%), cool down to 10-40°C, add 35 grams of MDI, 32 grams of carbodiimide-modified MDI, 10 ppm of polymerization inhibitor, and 1010 of anti-aging agent: 3 g, react at 80-85°C for 1.5-2.5 hours, cool down to 30-50°C, and bottle.
[0017] When used, the adhesive is mixed with cork particles in a ratio of 1:10.
Embodiment 2
[0019] Add 10 grams of polyether polyol (DL-3000), 5 grams of polyether polyol (DL-2000) and 5 grams of polyether polyol (MN-3050) into a three-necked bottle at room temperature, and raise the temperature to 80°C-100°C Stir under vacuum, dehydrate and degas until the moisture is qualified, lower the temperature to 10-40°C, add 38 grams of MDI, 40 grams of carbodiimide-modified MDI, 10 ppm of polymerization inhibitor, anti-aging agent (BHT): 2 grams, 80 React at -85°C for 1.5-2.5 hours, cool down to 30-50°C, and bottle.
[0020] When used, the glue is mixed with cork particles in a mass ratio of 1:10.
Embodiment 3
[0022] Add 30 grams of polyether polyol (MN-3050) into a three-necked bottle at room temperature, stir at 80°C-100°C, vacuumize and dehydrate until the water is qualified, then cool down to 10-40°C, add 30 grams of MDI, and carbonize Diimine-modified MDI 39 grams, polymerization inhibitor 10 ppm, anti-aging agent (BHT): 1 gram, react at 80-85 °C for 1.5-2.5 hours, cool to 30-50 °C, and bottle.
[0023] When used, the adhesive is mixed with cork particles in a mass ratio of 1:8.
[0024] cork products
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