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Special coloring agent of diammonium phosphate compound fertilizer and preparation method thereof

A diammonium phosphate and colorant technology, which is applied in ammonium orthophosphate fertilizers, alkaline orthophosphate fertilizers, phosphate fertilizers, etc., can solve the problems of dark color, poor smoothness and roundness of DAP particles, and failure of iron oxide red. Achieve the effects of avoiding the formation of phosphate complexes, improving strength and roundness, enhancing dispersion and adhesion

Inactive Publication Date: 2010-03-17
中化重庆涪陵化工有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Due to the excessive use of inorganic pigment iron oxide red in the commonly used DAP internal colorant, phosphate complexes are formed after it reacts with phosphoric acid in the pre-neutralized acid slurry, which not only degrades water-soluble P205 into Soluble P205 will also invalidate the iron oxide red as the red matrix, resulting in the dark color of the DAP particles obtained after secondary neutralization granulation, drying and sieving, poor smoothness and roundness, and requires secondary external coloring. Qualified brown DAP particles can be obtained
Not only the colorant consumption is high, but also the process is complicated, and the processing cost is as high as 80 yuan / t product

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] Preparation process: Add 567kg of water into a vertical circular reaction tank with agitator through a metering pump, turn on the agitator, and add 400kg of humate, carbon black and 30kg, acid black 40kg, acid scarlet 20kg, after stirring for 20 minutes, add 10kg of sodium hexametaphosphate, and continue stirring for 90 minutes to prepare the special colorant for diammonium phosphate compound fertilizer.

[0035] Coloring effect test: use the internal colorant product of this formula to carry out 72h continuous scale-up industrial test on a 300kt / a diammonium phosphate (DAP) device. It is measured that the particles are brown at 7.8kg / tDAP, and the coloring effect is better.

Embodiment 2

[0037] Preparation process: add 400kg of water into a vertical circular reaction tank with agitator through a metering pump, turn on the agitator, and add 500kg of humate, carbon black and 1kg, acid black 20kg, acid scarlet 10kg, after stirring for 30 minutes, add 2kg of sodium hexametaphosphate, and continue stirring for 60 minutes to prepare the special coloring agent for diammonium phosphate compound fertilizer.

[0038] Coloring effect test: use the internal colorant product of this formula to conduct a 72h continuous industrial scale-up test on a 300kt / a diammonium phosphate (DAP) device. It is measured that the particles are dark brown at 7.0kg / tDAP, and the coloring effect is better.

Embodiment 3

[0040] Preparation process: Add 445kg of water into the vertical circular reaction tank with agitator through a metering pump, turn on the agitator, and add 450kg of humate and carbon black successively under the action of high-intensity agitation with the agitator rotating at 600r / min 5kg, acid black 30kg, acid scarlet 15kg, after stirring for 25 minutes, add 5kg of sodium hexametaphosphate, and continue stirring for 70 minutes to prepare the special colorant for diammonium phosphate compound fertilizer.

[0041] Coloring effect test: use the internal colorant product of this formula to conduct a 72h continuous industrial scale-up test on a 300kt / a diammonium phosphate (DAP) device. It is measured that the particles are brown at 7.8kg / tDAP, and the coloring effect is better.

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PUM

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Abstract

The invention discloses a special coloring agent of a diammonium phosphate compound fertilizer, comprising the following constituents: 40-50 parts of humic acid salt, 0.1-3 parts of carbon soot, 2-4 parts of acid black, 1-2 parts of acid brilliant scarlet, 0.2-1 part of sodium hexametaphosphate, and 40-56.7 parts of water by weight parts; the preparation process is that: the material is prepared by weight parts, water is added in a vertical round reaction tank, and then the humic acid salt, the carbon soot, the acid black and the acid brilliant scarlet are added and are stirred uniformly, andthen sodium hexametaphosphate is added, the mixture is stirred continuously and uniformly, so as to obtain the special coloring agent of the diammonium phosphate compound fertilizer; the invention solves the problems that the diammonium phosphate particles produced under an acid slurry condition are easy to decolorize and the chromaticity is unstable; the special coloring agent of the diammonium phosphate compound fertilizer is green and environmental-protection, has no pollution and is beneficial to the growth of crops; the product is in a liquid state and transported closely, and has convenient usage; the raw material is cheap and easy to obtain, the cost is low and the economic benefit is good.

Description

technical field [0001] The invention relates to a coloring agent, especially an internal coloring agent specially used for diammonium phosphate compound fertilizer. Background technique [0002] Diammonium phosphate (DAP) compound fertilizer has the reputation of "the king of chemical fertilizers". However, due to the use of different phosphate rock raw materials and different neutralization granulation reactors, the color of the produced particles varies between white, gray, beige, and light blue. In order to make diammonium phosphate (DAP) compound fertilizer granules For beautiful appearance, uniform color or color marking for products of different brands, it is necessary to use colorants to transform the particles into colorful appearances such as coffee, golden yellow, green, blue, etc., in order to achieve the above goals. The coloring and anti-caking of diammonium phosphate (DAP) compound fertilizers are often separated. The internal coloring of the product (called i...

Claims

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Application Information

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IPC IPC(8): C05G3/00C05B7/00
Inventor 王川盛勇毛克万李家红封中国
Owner 中化重庆涪陵化工有限公司
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