Method for preparing nano composite material

A technology for nanocomposite materials and multi-wall carbon nanotubes is applied in the field of preparation of nanocomposite materials, which can solve the problems of poor performance uniformity of composite materials, low dispersion degree of multi-wall carbon nanotubes, affecting the application performance of composite materials, and the like. The effect of increasing the degree of impact and increasing the impact strength

Inactive Publication Date: 2012-05-30
HEILONGJIANG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, when polymer-based composites are used as reinforcing materials, the agglomeration phenomenon affects the application performance of composite materials. This is because the surface atoms of multi-walled carbon nanotubes are under an asymmetric force field and have high surface energy and surface Binding energy, it is easy to combine with other atoms to form agglomeration
In order to prepare multi-walled carbon nanotube polymer-based composite materials, most of the domestic and foreign countries use mechanical force at present, and adopt melting, single-screw or twin-screw extrusion. The degree of dispersion in the material matrix is ​​low, and the uniformity of the performance of the composite material is poor

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] The preparation method of the nanocomposite material is to pre-mix the multi-walled carbon nanotubes in a xylene solvent by ultrasonic waves, then mix the multi-walled carbon nanotubes and low-density polyethylene at 110°C, and finally mix the multi-walled carbon nanotubes Mix and disperse with low-density polyethylene at 180°C.

Embodiment 2

[0020] In the preparation method of the nanocomposite material described in Example 1, the pre-mixing of multi-walled carbon nanotubes in a xylene solvent by using ultrasonic waves refers to weighing 0.5g of multi-walled carbon nanotubes, adding 80ml di After toluene solvent, carry out ultrasonic dispersion, after 30min, further carry out stirring 700r / min to disperse for 1h.

Embodiment 3

[0022] In the preparation method of the nanocomposite material described in embodiment 1 or 2, the described mixing of multi-walled carbon nanotubes and low-density polyethylene at 110°C means adding 2.5-10g of low-density polyethylene to keep 110 ℃, make the polyethylene reach and maintain the molten state, stir at a speed of 700r / min, and remove the xylene solvent from the mixed solution in a blast drying oven at 120 ℃ after 3 hours.

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Abstract

The invention belongs to a method for preparing a nano composite material. A multi-walled carbon nano-tube has excellent mechanical properties and conductivity and a unique nano effect of a one-dimensional nanostructure, due to having higher surface energy and surface binding energy, the surface atoms of the multi-walled carbon nano-tube are more easily agglomerated when the multi-walled carbon nano-tube is used as a reinforced material of a polyvinyl composite material with low density, thereby the multi-walled carbon nano-tube has a low dispersion degree in a polyethylene matrix with low density, and an application performance of the composite material is influenced. The method for preparing the nano composite material comprises the following steps: the multi-walled carbon nano-tube is mixed in xylene solvent in advance by using ultrasonic waves; then, the multi-walled carbon nano-tube is mixed with polyethylene solution with low density at 110 DEG C; and finally, the multi-walled carbon nano-tube and polyethylene with low density are internally mixed and dispersed at 180 DEG C. The invention provides the method for preparing the nano composite material by the dispersion of the multi-walled carbon nano-tube in the polyethylene with low density.

Description

Technical field: [0001] The invention relates to a preparation method, in particular to a preparation method of a nanocomposite material. Background technique: [0002] Multi-walled carbon nanotubes have excellent mechanical and electrical properties and the unique nano-effects of their unique one-dimensional nanostructures, making them useful in the preparation of composite materials with super-strong mechanical properties and in the research and development of a new generation of polymers with electrical and optoelectronic properties. played an important role in the field of composite materials. However, when polymer-based composites are used as reinforcing materials, the agglomeration phenomenon affects the application performance of composite materials. This is because the surface atoms of multi-walled carbon nanotubes are under an asymmetric force field and have high surface energy and surface Binding energy, it is very easy to combine with other atoms to form agglomer...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L23/06C08K7/00C08K3/04C08J3/20B29B7/28
Inventor 赵东宇赵冬梅王淑红
Owner HEILONGJIANG UNIV
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