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Nitrogen coated slow release fertilizer

A coating and fertilizer technology, applied in fertilization devices, fertilizer mixtures, agriculture, etc., can solve the problems of non-degradable coating, environmental pollution, and short release period, and achieve good slow-release application effect, high fertilizer content, and long release period effect

Inactive Publication Date: 2009-07-22
NANJING UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, most of the coatings of slow-release chemical fertilizer products cannot be degraded, such as epoxy resin, polyurethane, polyethylene, polypropylene, polyvinyl chloride and other coatings will remain in the soil and pollute the environment, especially the coatings are mostly not fertilizers, so now Organic coatings of slow-release fertilizer products are useless to crops
The development of nitrogen-coated slow-release fertilizers is a good expectation in the field of coated slow-release fertilizers. However, the release period of nitrogen-coated slow-release fertilizers is relatively short (for example, the release period is very short when amino resin-coated fertilizers are purely used). , for example, when the thickness of the coating is about 200 μm and soaked in water at about 25°C, the fertilizer core will be completely dissolved in only a few days), so good practical application effects cannot be obtained or the practical surface is too narrow

Method used

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  • Nitrogen coated slow release fertilizer

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] Add granular industrial urea with a particle size of 2.5 to 3.5mm into the drum coating equipment, and keep the granular urea in a flowing state, and keep the temperature of the granular urea in the drum at 90°C. Spray the aqueous solution of urea-formaldehyde resin prepolymer (urea-formaldehyde resin prepolymer is prepared by reacting urea and formaldehyde with a urea:formaldehyde molar ratio of 1:1.6) slowly on the surface of granular urea, and spray until the quality of the urea-formaldehyde resin coating reaches the final product 24% of the total mass of nitrogen-coated slow-release urea (thickness is about 175 μm), when the surface is viscous, add excess calcium carbonate (particle size 3 μm) to make the surface of the coating stick to a layer of calcium carbonate, and then fully dry Remove the water in the coating, fully solidify the urea-formaldehyde resin in the coating, sieve and remove the unadhered calcium carbonate, and obtain the nitrogen coated slow-release...

Embodiment 2

[0023] Add granular industrial urea with a particle size of 2.5 to 3.5mm into the drum coating equipment, and keep the granular urea in a flowing state, and keep the temperature of the granular urea in the drum at 90°C. Spray the aqueous solution of urea-formaldehyde resin prepolymer (urea-formaldehyde resin prepolymer is prepared by reacting urea and formaldehyde with a urea:formaldehyde molar ratio of 1:1.6) slowly on the surface of granular urea, and spray until the quality of the urea-formaldehyde resin coating reaches the final product 22% (thickness is about 158 ​​μ m) of the total mass of nitrogen-coated type slow-release urea, when the surface is viscous, add excessive nano-calcium carbonate (particle diameter 50nm) so that the coating surface sticks and wraps one layer of nano-calcium carbonate, and then Fully dry to remove the water in the coating, fully solidify the urea-formaldehyde resin in the coating, and sieve to remove the unadhered nano-calcium carbonate to ob...

Embodiment 3

[0025]Add granular industrial urea with a particle size of 2.5 to 3.5mm into the drum coating equipment, and keep the granular urea in a flowing state, and keep the temperature of the granular urea in the drum at 90°C. Slowly spray the melamine-formaldehyde resin prepolymer aqueous solution (the melamine-formaldehyde resin prepolymer is prepared by reacting melamine and formaldehyde with a melamine:formaldehyde molar ratio of 1:3) on the surface of granular urea until the melamine-formaldehyde resin Coating quality reaches 20% (thickness is about 140 μ m) of the total mass of final product nitrogen coating type slow-release urea, sprays excessive white carbon black-alumina mixed powder (silica particle diameter 40nm, The alumina particle size is 2 μm, and the mass ratio of silica: alumina is 9:1) so that the surface of the coating is coated with a layer of silica-alumina mixed powder, and then fully dried to remove the water in the coating, and the coating The melamine-formald...

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Abstract

The invention discloses a nitrogenous envelope slowed release fertilizer, which comprises a fertilizer core and an envelope outside the fertilizer core; the envelope is an amino resin envelope; fertilizer-resistance inorganic padding with the grain diameters equal to or less than 3 microns are wrapped on the surface of the envelope; wherein, the amino resin can be urea formaldehyde resin and / or melamine resin. The fertilizer-resistance inorganic padding wrapped on the surface of the envelope are better to be nano padding with the grain diameters equal to or less than 1 micron, and can be one or more than one of nano calcium carbonate, white carbon black and nano carbon black. The wrapped (nano) fertilizer-resistance inorganic padding can comprise fertilizer-permeable padding and / or the fertilizer-resistance inorganic padding with the grain diameters more than 3 microns. The fertilizer-permeable padding can be one or more than one of natural organic powder, clay powder, water-soluble grains, and the like. The thickness of the envelope is better to be between 50 and 220 mu m. The organic envelope body of the slowed release fertilizer is harmless to the environment, and is a nutriment in a fertilizer, with low cost and long and adjustable release period.

Description

1. Technical field [0001] The invention relates to a film-coated slow-release chemical fertilizer, in particular to a nitrogen film-coated slow-release chemical fertilizer, which belongs to the field of chemical fertilizer industry. 2. Background technology [0002] Slow-release chemical fertilizers meet the requirements of environmental protection and sustainable social development, and will become the mainstream of agricultural chemical fertilizers in the future and the development direction of agricultural chemical fertilizers in the world. However, most of the coatings of slow-release chemical fertilizer products cannot be degraded, such as epoxy resin, polyurethane, polyethylene, polypropylene, polyvinyl chloride and other coatings will remain in the soil and pollute the environment, especially the coatings are mostly not fertilizers, so now Organic coatings of slow-release fertilizer products are substances that are not useful to crops. The development of nitrogen-coa...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C05G3/08C05G3/90
Inventor 应宗荣应榜元刘海生王志高
Owner NANJING UNIV OF SCI & TECH
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