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Film inhibitor and uses thereof

A corrosion inhibitor and film-forming technology, applied in the field of film-forming corrosion inhibitors, can solve problems such as existing risks and difficult adjustments, and achieve the effects of strong hydrophobicity, stable physical and chemical properties, and strong corrosion resistance

Inactive Publication Date: 2008-06-11
WUHAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, when the film-forming corrosion inhibitor mainly based on imidazoline derivatives is used at high temperature, the pH value of the solution will drop. The pH value of the water is adjusted to between 9.8 and 10.2, which is difficult and risky

Method used

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Examples

Experimental program
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Embodiment Construction

[0017] The present invention will be further described below in conjunction with specific examples.

[0018] Mixing 30-50% of octadecylamine, 20-30% of imidazoline amide and 50-20% of carbohydrazide is mixed to prepare a film-forming corrosion inhibitor aqueous solution with 10-20% by mass.

[0019] The step that film-forming corrosion inhibitor of the present invention is applied in shutdown protection is:

[0020] (1) The sliding parameter shutdown process of the generator set from the running state to the standby state.

[0021] (2) The film-forming corrosion inhibitor solution is dissolved and diluted with desalted water or condensed water greater than 2 times the volume of the agent for 1 hour in order to speed up the process of adding the agent.

[0022] (3) Before adding the film-forming corrosion inhibitor to the water supply system, exit the condensate polishing system to avoid resin pollution caused by direct contact between the film-forming corrosion inhibitor and ...

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PUM

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Abstract

The invention discloses a filming corrosion inhibitor, which at least comprises 30 to 50 percent of octadecylamine, 20 to 30 percent of imidazoline amide, and reducing agent carbohydrazide being the rest, the above proportion is mass percentage. Under the condition that the temperature is 150 to 500 DEG C, the concentration of the filming corrosion inhibitor is 10 to 35 ppm, the pH valve is 7 to 11, and the time duration is 1 h to 10 min, the filming corrosion inhibitor can produce a compact protective film on the metal surface, and the function of preventing the metal to be corroded in the atmospheric environment is realized, especially the invention can be applied during the thermal power plant to stop the boilers for protection, the protective film with strong hydrophobicity and good erosion resistance can be produced on the metal surface inside the water vapor system of the thermal equipment, and the thermal equipment can be protect from being corroded for more than 8 months during the exposition in atmospheric environment, simultaneously, the invention has certain cleaning, uncovering, and removing function to the incrustation and the corrosion product on the metal surface of the thermal system, the probability of the thermal equipment corrosion and the four-tube blasting is reduced, the invention is advantageous for extending the acid pickling cycle of the boiler, the service life of the equipment is prolonged, the security is enhanced, and the economic benefit is increased.

Description

technical field [0001] The invention relates to a film-forming corrosion inhibitor and its application, in particular to a film-forming corrosion inhibitor and its application in preventing the shutdown and corrosion of thermal power plants, and belongs to the technical field of film-forming corrosion inhibitors. Background technique [0002] Regardless of the parameters and capacity of the thermal power generating set, it is inevitable to shut down for maintenance or be in a standby state. If effective protection measures are not taken, the water vapor system of the shutdown unit will be exposed to the atmospheric environment, and a large amount of corrosion will occur. Boiler shutdown corrosion will not only bring huge direct and indirect economic losses, but also greatly endanger the safe operation of thermal units, which is extremely harmful. The octadecylamine shutdown protection method is based on the fact that octadecylamine can form a monolayer or multilayer hydroph...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23F11/14
Inventor 曹顺安
Owner WUHAN UNIV
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