Cashew shell modified alkyd resin and preparation method thereof
A technology of cashew nut shell oil and a manufacturing method, which is applied in the field of manufacturing and application of modified phenolic resin, can solve problems such as complex production process, increased cost, and difficulty in quality consistency, and achieve simple manufacturing process, reduced usage, and free phenol low effect
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example 1
[0011] Example 1. Take 400 g of phenol and add 100 g of cashew nut shell oil. Heat to 80°C under full stirring, use hydrochloric acid to adjust the acidity pH to 3-4, and cool down after two hours of reaction. When the temperature is about 60°C, add 350g (37%) formaldehyde solution, continue to adjust the pH value to be about 2, in a reactor with a reflux device, heat up to 97°C for reaction, keep warm for 50 minutes, and then dehydrate at normal pressure After 40 minutes, decompression and dehydration are carried out. After sampling and analysis, when the dropping point is about 100 ℃, the negative pressure discharge is released. The main indicators of the obtained products are as follows:
Viscosity: 40S (4# coating cup)
Dropping point: 102℃
Gel time: 50S (150℃)
Yield 112%
example 2
[0012] Example 2: Other conditions were the same as Example 1, 350 g of phenol, 150 g of cashew nut shell oil, 340 g of formaldehyde, and the catalyst was sulfuric acid. During the reaction, dehydration at normal pressure is no longer carried out. After the heat preservation reaction, dehydration under reduced pressure is carried out directly. Due to the large foaming in the later stage, a defoaming agent is required. And add a certain mass of barium hydroxide to neutralize the sulfuric acid to make the resin neutral. The main indicators of the obtained products are as follows:
Viscosity: 48S (4# coating cup)
Dropping point: 105℃
Gel time: 45S
Free phenol: ≤5
Yield 118%
example 3
[0013] Example 3: 400 g of phenol and 100 g of cashew nut shell oil were reacted under acidic catalyst conditions for two hours, washed with water, then added with 450 g (37%) of formaldehyde, the catalyst was ammonia water, and the pH value was adjusted to 11-12. When the cloud point of the reaction occurs, the reaction is continued for 30 minutes, heated, dehydrated under reduced pressure, and the temperature is kept below 100 °C.
Index: viscosity 42S (4# coating cup)
Dropping point: 101℃
Gel time: 42S (180℃) (without adding curing agent)
Yield 122%
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