Fluorescent substances for vacuum ultraviolet radiation laser light-emitting devices
A technology of vacuum ultraviolet rays and fluorescent materials, which is applied in the field of fluorescent materials and can solve problems such as insufficient brightness and reduced brightness
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Embodiment 1
[0033] Weigh the raw material, i.e. calcium carbonate (CaCO produced by WAKOJUNYAKU Co., Ltd. 3 ), strontium carbonate (SrCO produced by WAKOJUNYAKU Co., Ltd. 3 ), europium oxide (Eu 2 o 3 ), basic magnesium carbonate (produced by WAKOJUNYAKU Co., Ltd. (MgCO 3 ) 4 Mg(OH) 2 ·5H 2 O) and silicon oxide (SiO produced by WAKO JUNYAKU Co., Ltd. 2 ), and mixed together so that CaCO 3 : SrCO 3 :Eu 2 o 3 :(MgCO 3 ) 4 Mg(OH) 2 ·5H 2 O: SiO 2 The molar ratio is 0.9215:0.0485:0.015:0.2:2. At 1200°C, with 2% (volume) H content 2 The resulting mixture was calcined for 2 hours under Ar flow, then ground, and then at 1200°C in a 2% (volume) content of H 2 Calcined for 2 hours under Ar flow. Thus, by the formula Ca 0.9215 Sr 0.485 Eu 0.03 MgSi 2 o 6 Indicates the composition of the fluorescent material. When this fluorescent material is under pressure of 6.7Pa (5×10 -2 Torr) or lower in a vacuum chamber, when irradiated with ultraviolet radiation using an exciter 146-n...
Embodiment 2
[0038] Weigh the raw material, i.e. strontium carbonate (SrCO produced by WAKOJUNYAKU Co., Ltd. 3 ), barium carbonate (BaCO produced by WAKOJUNYAKU Co., Ltd. 3 ), europium oxide (Eu 2 o 3 ), basic magnesium carbonate (produced by WAKOJUNYAKU Co., Ltd. (MgCO 3 ) 4 Mg(OH) 2 ·5H 2 O) and silicon oxide (SiO produced by WAKO JUNYAKU Co., Ltd. 2 ), and mixed together so that SrCO 3 : BaCO 3 :Eu 2 o 3 :(MgCO 3 ) 4 Mg(OH) 2 ·5H 2 O: SiO 2 The molar ratio is 2.28:0.57:0.075:0.2:2. At 1200°C, with 2% (volume) H content 2 The resulting mixture was calcined under an Ar atmosphere for 2 hours. From this we get the formula Sr 2.28 Ba 0.57 Eu 0.15 MgSi 2 o 8 Indicates the composition of the fluorescent material. When this fluorescent material is under pressure of 6.7Pa (5×10-2 Torr) or lower in a vacuum chamber, when irradiated with ultraviolet radiation using an exciter 146-nm lamp (model: H0012 produced by USHIODENKI Co., Ltd.), it emits a luminance of 30cd / m 2 Blu-...
Embodiment 3
[0040] Weigh the raw material, i.e. barium carbonate (BaCO3 produced by KANTOKAGAKU Co., Ltd. 3 ), europium oxide (Eu 2 o 3 ), magnesium oxide (MgO produced by KANTOKAGAKU Co., Ltd.), and silicon oxide (SiO 2 ), and mixed together so that BaCO 3 :Eu 2 o 3 :MgO:SiO 2 The molar ratio is 1.98:0.01:1:2. Add 0.1 mole of B to 1 mole of product 2 o 3 As a flux, the resulting mixture was thoroughly wet mixed in acetone with a mortar and then dried. The mixed raw material thus obtained was placed in a stainless steel mold, and then pressurized at 40 MPa to form pellets with a size of 15 mm (diameter) x 3 mm (thickness). The obtained pellets were placed in an aluminum crucible, and heated at 1200 °C under H 2 , Ar composition ratio of 5%: 95% (volume) atmosphere for calcination for 3 hours. From this we get the formula Ba 1.98 Eu 0.02 MgSi 2 o 7 Indicates the composition of the fluorescent material. When this fluorescent material is under pressure of 6.7Pa (5×10 -2 Torr...
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