Catalyst for autothermal reformation of gasoline or diesel oil, preparation and application

Abstract

The invention involves an accelerant with high activity / selectivity, good stability and strong resistance to sulfur poisoning which is used for gasoline self-heating reforming hydrogen production process and its preparation and usage, and it belongs to energy resource and oil chemical industry catalysis material and its production technology field. The load-type metal catalyst provided by the invention is a rare earth oxides modified loading metal catalyst, the content of the rare earth oxides in the catalyst is 0.4%-20%, the content of active metal component is 0.3%-5%, the content of the carrier is 75%-99.3%. Compared with the prior technology, the hydrogenation catalyst need not add additional manufacturing equipment and has performance of high activity / selectivity, good stability and strong resistance-sulfur poisoning. The catalyst is easy to manufacture, cost of manufacturing is small and cost is very low, the prepared catalysts can meet the strength requirement of actual process to the catalyst, etc.

Description

technical field [0001] The present invention relates to gasoline / diesel autothermal reforming hydrogen production technology, and in particular provides a catalyst with high activity / selectivity, good stability and strong resistance to sulfur poisoning for the gasoline autothermal reforming hydrogen production process, and provides The preparation method of the hydrogen production catalyst belongs to the technical field of energy and petrochemical catalytic materials and their manufacture. technical background [0002] h 2 -O 2 Proton exchange membrane fuel cell (PEMFC) is a high-efficiency and environmentally friendly technology, with the advantages of no pollutant emissions, high efficiency (40-60%), no noise, fast start-up, etc. It is widely used in electric vehicles, small mobile electronic devices, homes or hospitals There are huge market prospects in terms of backup power and so on. Since hydrogen storage technology is still far away from practical requirements, the...

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Problems solved by technology

The catalyst disclosed in Chinese patent (Application No.: 200510111783.1) has good catalytic activity and selectivity for the reforming hydrogen production reaction of C1-C16 hydrocarbons in the presence of sulfur, but the rare earth oxide as the carrier The catalyst has problems such as difficult molding and poor mechanical strength of the catalyst; the catalyst disclosed in the Chinese patent (Application No.: 200610024934.4) has a good performance in the reforming hydrogen production reaction of C1-C16 hydrocarbons under the condition of the presence of 300 ppm sulfur. Catalytic activity and selectivity, but the embodiment mainly provides the reaction results on model compounds such as isooctane, hexadecane and methane, only the result of 50h on the investigation of commercial gasoline autothermal reforming reaction performance, and there is no Effects of commercial diesel autothermal reforming reaction performance, especially catalyst life

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