Surfactant Additives for Stimulating Subterranean Formation During Fracturing Operations
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[0040]Regain permeability tests were performed for various surfactants using a 150 μD Crab Orchard Sandstone core to simulate a tight gas formation. Table 1 summarizes the composition of the surfactants including decyl amine oxide (C10AO), cocoamidopropyl betaine (CFS-485), dodecyl amine oxide (C12AO), microemulsion surfactant / solvent additive (commercially available as GASPERM 1000™ from Halliburton Energy Services, Inc.), microemulsion additive (commercially available as MA-844 from CESI Chemical), KCl brine, and amphoteric surfactant. Some of the samples also include a cosurfactant (pyrrolidin commercially available as SURFADONE® from ISP Performance Chemicals or butanol). The tests were performed according to the following description.
TABLE 1RegainPerme-SurfactantCosurfactantRatioability (%)decyl amine oxide (C10AO)pyrrolidin ring1:276(Surfadone ®)cocoamidopropyl betaine (CFS-485)butanol1:5100dodecyl amine oxide (C12AO)butanol1:4100microemulsion surfactant / solvent56additive (Gas...
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