Concentrated liquid soap formulations having readily pumpable viscosity
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[0093]Using the rheological protocol noted above, a commercial soap bar was tested. The soap bar represents the low water soap formulations which are in the prior art. These formulations have a high viscosity and can not be dispensed from a tube. The force which would be required for dispensing a soap bar according to the applied rheological protocol is 5160 N. This force is well above the critical range of the subject invention of 0-300 N.
[0094]For the raw materials used in the example formulations the chain length distributions are given in the table below:
HTCoconutLauricMyristicPalmiticCommercialChain LengthFatty AcidAcidAcidAcidStearic AcidShort Chain00000(Capric C1000000(+C8) (wt %)Lauric C1255.1100000(+C11) (wt %)Myristic C1421.9010022(+C13) (wt %)Palmitic C1611.4009245(+C15) (wt %)Stearic C1811.400652(+C17) (wt %)Long0.20000Saturates >=C19 (wt %)Other00001
Examples 1-3 and Comparatives A & B
[0095]For a mixture of short chain potassium soaps, a critical window of neutrality exi...
examples 7-9
[0101]Like co-solvents, synthetic surfactant can also be used to reduce or maintain the dispensing force below 300 N, particularly low temperature dispensing. Examples 7-9 are two formulations which demonstrate the effect of synthetic surfactants on partially neutralized soap formulations. When compared to Example 3, the addition of synthetic surfactants reduces the dispensing force at both 23° C. and 12° C.
Ingredients by wt %Formulation Number789HT Coco Fatty Acid37.8%37.8%37.8%Myristic Fatty Acid15.1%15.1%15.1%KOH (45 wt %)26.5% 0.0% 0.0%KOH (85 wt %) 0.0%14.0%14.0%SLES (70 wt %) 9.5% 9.5% 0.0%CAPB (28 wt %) 8.5% 8.5% 0.0%Sodium Lauryl Sarcosinate (30 wt 0.0% 0.0%30.1%%)DPG 0.0% 3.0% 3.0%Water 2.6%12.1% 0.0%Soap:Fatty Acid10.5010.4910.49Solvent Concentration30.0%30.0%30.0%Syndet Concentration 9.0% 9.0% 9.0%Dispensing Force @ 23° C.51.511.26.7Dispensing Force @ 12° C.46091482% of Fatty acid and soap with16.45% 16.45% 16.45% chain length >C14% of neutralization of final89.98% 89.97%...
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