Security document with a transparent pattern and a process for producing a security document with a transparent pattern
a security document and transparent technology, applied in the field the production process of security documents with transparent patterns, can solve the problems that the prior art fails to teach the realization of a permanent transparent pattern in the self-supporting film itself or a means, and achieves the effect of higher melting point and higher melting poin
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invention examples 1 to 11
[0219]The ca. 1100 μm thick extrudates of INVENTION EXAMPLES 1 to 11 all with 2% by weight of titanium dioxide and 15% by weight of SAN 06 were produced by mixing the ingredients in Table 8 in the proportions given in Table 8 and then drying the mixture at 150° C. for 4 hours under vacuum (<100 mbar) before melting in a PET-extruder, extrusion through a sheet die and cooling to produce the extrudates of INVENTION EXAMPLES 1 to 11 having a density of ca. 1.3 g / mL as summarized in Table 8.
TABLE 8SANUVITEXTiO2ExampleTO4PET04SAN[wt OB-one[wt Densitynr.[wt %][wt %]type%][ppm]%][g / mL]18300615—2.01.294258250615—2.01.289341.541.506151002.01.284433.349.706151002.0532.350.706151002.0632.350.706151002.0726.2956.7106151002.0825.2557.7506151002.09255806151002.01.3041024.358.706151002.011—830615—2.01.299
[0220]Longitudinal stretching was carried out for each extrudate as described in COMPARATIVE EXAMPLES 1 to 3 under the conditions given in Table 9. The expected thickness is the thickness based on...
invention examples 12 to 16
[0228]The ca. 1100 μm thick extrudates of INVENTION EXAMPLES 12 to 16 all with 2% by weight of titanium dioxide were produced as described for INVENTION EXAMPLES 1 to 11 with 15% by weight of SAN or 15% by weight of ABS (MAGNUM 8391) and different weight ratios of TO4 and PET04 as summarized in Table 13.
TABLE 13InventionUVITEXTiO2ExamplePET02PET04MAGNUMSAN 06OB-one[wtnr.[wt %][wt %]8391 [wt %][wt %][ppm]%]10283015——2.010341.241.8—151002.010432.350.7—151002.01053251—151002.0106—83—151002.0
[0229]Stretching in the length direction was carried out for each extrudate as described in COMPARATIVE EXAMPLES 1 to 3 under the conditions given in Table 14. The expected thickness is the thickness based on the extrudate thickness and longitudinal as observed for non-voided films.
TABLE 14InventionLongitudinal stretchingExampleforcetemperatureThickness [μm]ODODnr.ratio[N / mm2][° C.]MeasuredExpectedTR924[X-rite]102 / LS13.68—3180.840.60 103 / LS1*3.37.973753331.080.96 103 / LS2*3.37.143330.9480.86 103 / LS3*...
invention examples 17 to 19
[0236]The ca. 1100 μm thick extrudates of INVENTION EXAMPLES 17 to 19 all with 2% by weight of titanium dioxide and 15% by weight of SAN 06 were produced as described for EXAMPLES 1 to 11 with different weight ratios of TO4 and PET04 as summarized in Table 20.
TABLE 20InventionPET02Example[%PET04SAN 06UVITEX OB-TiO2nr.by wt][% by wt][% by wt]one [ppm][% by wt]1732.350.7151002.018—83151002.019—83151002.0
[0237]Stretching in the length direction was carried out for each extrudate as described in COMPARATIVE EXAMPLES 1 to 3 under the conditions given in Table 21. The expected thickness is the thickness based on the extrudate thickness and longitudinal as observed for non-voided films.
TABLE 21InventionLongitudinal stretchingExampleforcetemperatureThickness [μm]ODODnr.ratio[N / mm2][° C.]measuredexpectedTR924[X-rite]17 / LS13.38.69036533317 / LS23.18.28038035518 / LS13.858—3201.241.0019 / LS13.628—3231.090.82
[0238]Transversal stretching was then performed on the length-stretched films with a stretch...
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