Low-odor dimethicone copolyol sulfosuccinate surfactant compositions

Abstract

Dimethicone copolyol sulfosuccinate surfactant compounds having low-odor characteristics are disclosed. The low-odor dimethicone copolyol sulfosuccinate is substantially free from propionaldehyde and acid-releasable precursors of propionaldehyde, thereby substantially eliminating the cosmetically undesirable odor characteristic of conventional dimethicone copolyol sulfosuccinate surfactants. The low-odor dimethicone copolyol sulfosuccinates are suitable for use as surfactants in household or personal care products and applications.

Description

FIELD OF THE INVENTION [0001] This invention relates to sulfosuccinate surfactants. More particularly, this invention relates to silicone-based sulfosuccinate surfactants having low-odor characteristics. BACKGROUND OF THE INVENTION [0002] Sulfosuccinate surfactants have been used in the cosmetic industry primarily to improve the mildness of skin cleansers, shampoos and other personal care products. Such surfactants are usually diesters or monoesters, with the monoester being preferred because of its mildness and foam enhancement properties. Prior to the development of dimethicone copolyol sulfosuccinates, which are disclosed in U.S. Pat. No. 4,717,498 to Maxon, which is incorporated herein by reference, primarily two half ester or monoester derivatives had been used for shampoos. Such derivatives included derivatives of monoalcohol amides, such as oleamide MEA, oleamide IPA and undecylenamide MEA, and derivatives of fatty alcohols and ethoxylated alcohols, such as lauryl, laureth an...

AI Technical Summary

Benefits of technology

[0012] The compositions of the present invention are preferably prepared by reacting the ethoxylated polyether side chains of a low-odor dimethicone copolyol with maleic anhydride to form a monoester, and then converting the monoester to a sulfosuccinate by sulfonation of the double bond with a metallic or amino alcohol sulfite. The dimethicone copolyol starting material utilized in the reaction is preferably substantially free from propionaldehyde and acid-releasable precursors thereof, such as propionaldehyde enol ethers. Metallic sulfite and amino salts can also be used either alone or in combination for sulfonation of the double bond. The resulting sulfosuccinate is a silicone-based surfactant, which exhibits mildness to the skin, excellent foam stabilizing properties, and has a low-odor characteristic suitable for use in household or personal care products and applications.

Problems solved by technology

One factor which has limited the use of dimethicone copolyol sulfosuccinates in cosmetics is that such surfactants typically exhibit a characteristic odor, which can be objectionable in some personal care and cosmetic products.

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