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Process for preparing hydrogenated C5/C9 copolymerized petroleum resin

A technique of copolymerizing petroleum resin and hydrogen-to-oil ratio, which is applied in the field of hydrogenated petroleum resin preparation to achieve the effect of expanding the application range, low bromine value, and mild hydrogenation reaction conditions

Inactive Publication Date: 2007-05-16
SINOPEC YANGZI PETROCHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Currently, about C 5 / C 9 Catalytic Hydrogenation of Copolymerized Petroleum Resins to Prepare Hydrogenated C 5 / C 9 The method of copolymerizing petroleum resin has not been publicly disclosed; and in this country, hydrogenation of C 5 / C 9 The production of copolymer resin is still blank

Method used

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  • Process for preparing hydrogenated C5/C9 copolymerized petroleum resin

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0048] In this example, the hydrogenation reaction device is a small-scale gas-liquid-solid medium-pressure hydrogenation reaction device with a catalyst loading capacity of 40ml, and a 1Cr18Ni9Ti fixed-bed reactor, a three-stage temperature-controlled reaction furnace, and an integrated preheating mixer are selected. The design pressure is 10Mpa, and the actual temperature control accuracy of the device is less than 1°C. The gas feed is measured by a gas mass flow controller, the tail gas is measured by a wet flow meter, and the gas raw material flow control range: 0 ~ 500ml / min (MAX). The liquid reaction material is measured by a double plunger metering pump, and the liquid flow control range: 0.1 ~ 100ml / h (MAX). Pressure detection uses a pressure sensor connected to a digital display meter, and an intelligent control digital display meter is used for temperature control and detection.

[0049] The hydrogenation catalyst adopts JH-1 type nickel-supported Al 2 o 3 Support...

Embodiment 2～8

[0053] Examples 2-8 realize the present invention at different hydrogenation reaction temperatures, and optimize the reaction temperature.

[0054] Concrete implementation process is the same as embodiment 1, selects the JH-1 catalyst among the embodiment 1 for use, catalyst volume 40ml, raw material concentration 20%, hydrogenation reaction pressure 3.0MPa, space velocity 0.5h -1 , Hydrogen oil ratio 600:1. The hydrogenated petroleum resin obtained is shown in Table 4 by changing the hydrogenation reaction temperature within the range of 190-280°C.

[0055] Table 4 Effect of reaction temperature

[0056]

[0057] Raising the reaction temperature can speed up the reaction speed, promote the hydrogenation reaction, and reduce the impurity content, but if the temperature is too high, it will cause degradation side reactions, and accelerate the carbon deposition on the catalyst, reducing the service life of the catalyst. As the reaction temperature increases, the colo...

Embodiment 9～13

[0059] Examples 9-13 realize the present invention under different hydrogenation reaction pressures, and optimize the reaction pressures.

[0060] The specific implementation process is the same as in Example 1, select the JH-1 catalyst in Example 1, the catalyst volume is 40ml, the raw material concentration is 20%, the hydrogenation reaction temperature is 250 ° C, and the space velocity is 0.5h -1 , Hydrogen oil ratio 600:1. The hydrogenated petroleum resin obtained is shown in Table 5 by changing the hydrogenation reaction pressure within the range of 1.0-6.0 MPa.

[0061] Table 5 Effect of reaction pressure

[0062] Example

[0063] As can be seen from Table 5, increasing the pressure can increase the reaction speed, which is conducive to the diffusion of raw materials to the catalyst, but increasing the pressure will increase the consumption of equipment investment and energy consumption. Considering the hydrogenation depth in terms of energy saving, reduce th...

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Abstract

The invention discloses a preparing method of hydrogenated C5 / C9 copolymerized oil resin, which comprises the following steps: dissolving C5 / C9 copolymer oil resin in the hydrogenation solvent; decoloring through adsorbing agent to proceed catalytic hydrogenating reaction with hydrogen in the fixed bed reactor at 220-270 Deg C under 2.0-8.0Mpa; setting the bulk air-speed at 0.1-1.0h-1 and hydrogen and oil rate at 300-3000:1; allocating the catalyst as load-patterned nickel catalyst with 35-50% Ni; adopting gamma-Al2O3 as carrier with specific area at 150-300m2 / g and hole conpacitance at 0.2-0.4ml / g; decompressing hydrogenated product; distilling to recycle solvent to obtain the product.

Description

technical field [0001] The present invention relates to a kind of preparation method of hydrogenated petroleum resin, particularly relate to a kind of hydrogenated C 5 / C 9 Preparation method of copolymerized petroleum resin. Background technique [0002] Petroleum resin is a by-product of petroleum cracking C 5 、C 9 Distillation is a kind of polymer obtained by catalytic polymerization. Since the first successful development of petroleum resin in the United States in 1945, there have been more and more varieties. According to the different raw materials used for polymerization, it can be divided into five categories (1) C 5 Aliphatic hydrocarbon resins, from C 5 Distillate obtained; (2)C 9 Aromatic hydrocarbon petroleum resins, composed of C 9 Distillate obtained; (3) aromatic hydrocarbon - aliphatic hydrocarbon copolymer resin, also known as C 5 / C 9 Copolymerized petroleum resin; (4) Dicyclopentadiene resin, also known as DCPD resin made from dicyclopentadiene or...

Claims

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Application Information

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IPC IPC(8): C08F240/00
Inventor 黄荣荣袁伟邦马江权周凯张艳松柏基业
Owner SINOPEC YANGZI PETROCHEM
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