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Mercury less zinc manganese carbon paste battery

A zinc-manganese-carbon, battery technology is applied in the field of mercury-free zinc-manganese-carbon paste batteries to achieve the effects of increasing discharge rate, good electrical conductivity, and improved weather resistance

Inactive Publication Date: 2005-05-25
重庆电池总厂有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0043] The object of the present invention aims at the problems existing in existing mercury-zinc-manganese-carbon paste batteries, especially R14 type and R20 type batteries in realizing mercury-free etc., to provide a kind of mercury-free zinc-manganese carbon paste battery, which is Through the improvement and innovation of the electrolyte system and corrosion inhibition technology, the mercury-free battery can be realized, and the discharge performance and storage performance of the battery can be greatly improved, and the pollution of the waste battery to the environment can be solved from the source of production.

Method used

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  • Mercury less zinc manganese carbon paste battery

Examples

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Effect test

example 1

[0091] Example 1: Preparation process of mercury-free zinc-manganese-carbon R20S paste battery without wrapping or binding

[0092] 1. Electrolyte formula

[0093] In each liter of electrolyte:

[0094] MgCl 2 ·6H 2 O 13.5%

[0095] NH 4 Cl 12.0%

[0096] ZnCl 2 8.0%

[0097] water balance

[0098] Additional addition: PVA 1.50g

[0099] B(OH) 3 0.30g

[0100] Electrolyte specific gravity 21.5-22.5 degrees Baume

[0101] Electrolyte pH value 5.0-6.0

[0102] 2. Slurry formula

[0103] Per liter of slurry:

[0104] Total Salt 26.5%

[0105] Powder 21.5%

[0106] water balance

[0107] Also added: InCl 3 0.15g

[0108] PVA 1.50g

[0109] B(OH) 3 0.30g

[0110] 3. Cell formula

[0111] Manganese carbon ratio 87:13 (natural MnO 2 )

[0112] Plus NH 4 Cl 13% (based on the total weight of manganese carbon)

[0113] Cell moisture 21.5-22.5% (Based on the weight of cell powder)...

example 2

[0128] Example 2: Preparation process of mercury-free zinc-manganese-carbon R14S paste battery without wrapping or binding

[0129] 1. Electrolyte formula

[0130] In each liter of electrolyte:

[0131] MgCl 2 ·6H 2 O 14.5%

[0132] NH 4 Cl 13.0%

[0133] ZnCl 2 9.0%

[0134] water balance

[0135] Additional addition: PVA 1.50g

[0136] B(OH) 3 0.30g

[0137] Electrolyte specific gravity 21.5-22.5 degrees Baume

[0138] Electrolyte pH value 5.0-6.0

[0139] 2. Slurry formula

[0140] Per liter of slurry:

[0141] Total Salt 27.5%

[0142] Powder 22.5%

[0143] water balance

[0144] Also added: BiCl 3 0.20g

[0145] PVA 1.50g

[0146] B(OH) 3 0.30g

[0147] 3. Cell formula

[0148] The ratio of manganese to carbon is 87:13 (of which electrolytic MnO 2 20%)

[0149] Plus NH 4 Cl 13% (based on the total weight of manganese carbon)

[0150] Cell moisture 20.5-21.5% (based on the weight o...

example 3

[0166] Example 3: Mercury-free zinc-manganese-carbon R6 cardboard battery

[0167] 1. Electrolyte formula

[0168] In each liter of electrolyte:

[0169] MgCl 2 ·6H 2 O 13.5%

[0170] NH 4 Cl 13.0%

[0171] ZnCl 2 9.0%

[0172] water balance

[0173] Additional addition: PVA 1.50g

[0174] B(OH) 3 0.30g

[0175] 16C Trimethylammonium Chloride 2.0g

[0176] Electrolyte specific gravity 21.5-22.5 degrees Baume

[0177] Electrolyte pH value 5.0-6.0

[0178] 2. Cell formula

[0179] Manganese carbon 87:13 (of which electrolytic MnO 2 25%)

[0180] Plus NH 4 Cl 13% (based on the total weight of manganese carbon)

[0181] Cell moisture 21.5-22.5% (Based on the weight of cell powder)

[0182] 3. Cell Specifications

[0183] Battery powder net weight 7.6-7.8g

[0184] Cell shoulder height 34.0-35.0mm

[0185] Cell molding density ≥2.00g / ml

[0186] 4. Others are the same as the traditional battery technology ...

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Abstract

The invention relates to a mercury-free zinc-manganese-carbon paste battery. Its electrolyte is mainly composed of MgCl2 and NH4Cl2, supplemented by three components of ZnCl2. There is no distinction between internal and external electrolytes. Each liter of electrolyte contains the following weight percentages The substance MgCl2 11.0-16.0%, NH4Cl 12.0-14.0%, ZnCl2 6.0-9.0%, the rest is water, add PVA 1.00-2.00g, B(OH) 3 0.20-0.40g, the specific gravity of the electrolyte is 20-25 wave Mido, pH 5.0-6.0. The battery uses a mercury-free corrosion inhibitor, which is mainly boron alcohol resin produced by PVA and B(OH)3, supplemented by 16C or 18C trimethylammonium chloride, or alcohol produced by PVA and B(OH)3 Based on boron resin, supplemented by InCl3 or BiCl3, the present invention realizes the mercury-free battery through the improvement of the electrolyte system and corrosion inhibition technology, and can greatly improve the discharge performance and storage performance of the battery, and can also solve the problem of waste batteries from the source of production. pollution of the environment.

Description

technical field [0001] The invention belongs to the technical field of batteries, in particular to a mercury-free zinc-manganese-carbon paste battery. Background technique [0002] There are two types of zinc-manganese batteries: zinc-manganese alkaline batteries and zinc-manganese carbon batteries. Zinc-manganese alkaline batteries use KOH or NaOH as electrolyte. NH for zinc-manganese carbon batteries 4 Cl and ZnCl 2 As electrolyte, zinc-manganese carbon battery presses NH 4 Cl or ZnCl 2 Two electrolyte systems are formed with different amounts, and the corresponding batteries are called ammonium-type batteries or zinc-type batteries. [0003] There are two types of zinc-manganese-carbon cylindrical batteries: cardboard structure and paste structure. The cardboard structure battery uses pulp paper as the isolation layer. Starch, Flour, Corrosion Inhibitor HgCl for Paste Structure Batteries 2 Mix it with the external electrolyte to form a slurry, and then heat the sl...

Claims

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Application Information

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IPC IPC(8): H01M6/04H01M6/06
Inventor 白云徐星亮杨林
Owner 重庆电池总厂有限公司
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