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Use method of reduced catalyst

A technology for regenerating catalysts and catalysts, applied in the petroleum industry, refining hydrocarbon oil, etc., can solve problems such as insufficient activity and difficult implementation, and achieve the effects of easy operation, simple method, and stable performance

Inactive Publication Date: 2004-04-14
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The patent USP4,888,316 suggests that the waste hydrorefining catalyst should be processed by grinding, adding alumina, molding and charcoal to prepare a reusable catalyst, but this method has the problems of difficulty in implementation and insufficient activity

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] A Regenerated MoNi / Al 2 o 3 See Table 1 for the activity changes of the hydrofinishing catalyst before and after being mixed with its fresh catalyst (the 3936 hydrofinishing catalyst produced by Fushun Petrochemical Company Catalyst Factory).

Embodiment 2

[0019] A Regenerated WMoNi / Al 2 o 3 See Table 1 for the activity changes of the hydrofinishing catalyst before and after being mixed with its fresh catalyst (FH-5 hydrofinishing catalyst produced by Wenzhou Huahua Group Co., Ltd.).

[0020] Example 1

Relative activity, %

Example 2

Relative activity, %

regenerated catalyst

88

regenerated catalyst

91

97v% regenerated catalyst

+3v% fresh catalyst

88

97v% regenerated catalyst

+3v% fresh catalyst

93

90v% regenerated catalyst

+10v% fresh catalyst

92

90v% regenerated catalyst

+10v% fresh catalyst

95

75v% regenerated catalyst

+25v% fresh catalyst

94

75v% regenerated catalyst

+25v% fresh catalyst

95

60v% regenerated catalyst

+40v% fresh catalyst

96

60v% regenerated catalyst

+40v% fresh catalyst

97

fresh catalyst

...

Embodiment 3

[0024] A Regenerated WNi / USY+Al 2 o 3 The activity changes of the hydrocracking catalyst before and after being mixed with its fresh catalyst (3905 hydrocracking catalyst produced by Fushun Petrochemical Catalyst Factory) are shown in Table 2.

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PUM

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Abstract

The present invention provides a method for using regenerated catalyst whose performance can not meet the requirements for original reaction, and is characterized by that small quantity of similar fresh catalyst can be mixed into regenerated catalyst, then its activity is evaluated, and according to its performance condition is can be respectively used, it can be used in original reaction process or degraded for use. Said invention utilizes mutual matching use of fresh catalyst and regenerated catalyst to attain the goal of fully-utilizing catalyst, reducing energy consumption, broadening application range of regenerated catalyst and raising efficiency.

Description

1. Technical field [0001] The invention relates to a method for using a regenerated catalyst, in particular to a method for using a regenerated catalyst whose reaction performance cannot meet the original reaction process. 2. Background technology [0002] Catalytic methods, such as hydrocracking and hydrofinishing, are often used in oil refining and chemical processes to economically treat raw materials and convert them into various useful end products. The catalysts used in these processes will gradually lose their activity during long-term operation, which is largely due to the deposition of carbon deposits on the catalyst surface. For many catalysts, the activity can be partially or completely restored by burning off carbon deposits for regeneration, and can still be used in industrial production. Some catalysts can be regenerated many times to achieve the purpose of saving energy and increasing efficiency. At the same time, waste of resources can also be reduced. [...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10G45/00
Inventor 张喜文凌凤香孙万富程仲佥王俐
Owner CHINA PETROLEUM & CHEM CORP
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