Development suppressing group-releasing magenta color coupler
A technology of coupler and base product, applied in the field of silver halide color photosensitive negative materials, can solve the problems of slow release speed of development inhibitor and high synthesis cost, improve image granularity and color reproducibility, low synthesis cost, and improve Effects of color reproducibility and sharpness effects
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[0015] (Exemplary compound MCP-ZB): 1-(2,4,6-trichlorophenyl)-3-[3-[(2,4-di-tertpentylphenoxy)acetamido]benzamide ]-4-[[5-[(4-methylphenoxy)methyl]-1,3,4-diazol-2-yl]mercapto]-5-pyrazolone.
[0016] 1. Intermediate
[0017] 1-(2,4,6-Trichlorophenyl)-3-[3-(2,4-Di-tertpentylphenoxy)acetamido]benzamido-4-bromo-5-pyrazolone Preparation.
[0018] Reaction formula: (Abbreviated as MCP parent compound) (Abbreviated as MCP parent bromide)
[0019] Operation method:
[0020] In a 250 ml three-necked flask equipped with a stirrer and a thermometer, add 20 g of MCP parent compound and 60 ml of DMF (dimethylformamide), cool the temperature of the reaction flask to 0~5°C, and add 1.44 ml of bromine dropwise for half an hour After the internal dripping is completed, naturally warm to room temperature, continue the reaction for 2 hours, then pour the reaction liquid into a solution consisting of 200 ml of water and 100 g of ice, stir, a large amount of white solid appears, filter, wash, filter...
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