Polarizing plate and optical display apparatus comprising the same
A polarizing plate and polarizer technology, applied in optics, optical components, nonlinear optics, etc., can solve problems affecting the polarizing function of the polarizing plate, and achieve the effect of minimizing penetration
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Embodiment 1
[0119] A polyvinyl alcohol film (VF-TS#2000, hydrophobic polyvinyl alcohol resin, thickness: 20 μm, Kuraray Co., Ltd.) washed with water at 25°C was subjected to swelling treatment in a water swelling bath at 30°C.
[0120] After the swelling treatment, the film was immersed in a dye bath containing an aqueous solution containing 1 mol / ml potassium iodide and 1 wt% boric acid at 30°C for 65 seconds. Thereafter, the membrane was immersed in a crosslinking bath containing an aqueous solution containing 2.5 wt% boric acid at 30°C for 30 seconds.
[0121] After the crosslinking treatment, the film was stretched at 55°C in a stretching bath containing an aqueous solution containing 2.5 wt% boric acid.
[0122] The polyvinyl alcohol film is stretched to a total elongation of 5.0 times its original length or more through washing treatment, swelling treatment, dyeing treatment, crosslinking treatment and stretching treatment. Then, the film was immersed for 10 seconds at 20° C. in a ...
Embodiment 2 to 4
[0127] Except as listed in Table 1, change the content in each dyeing bath, crosslinking bath and stretching bath and the concentration of boric acid in the stretching bath, stretching temperature and / or drying temperature, in the same manner as Example 1 Manufacture of polarizers and polarizing plates.
Embodiment 5
[0129] A photocurable adhesive comprising: (meth)acrylic compounds including hydroxyl-containing (meth)acrylates, epoxy compounds including cycloaliphatic epoxy resins, cationic photopolymers including onium salts was prepared. initiators, and phosphorous-based photoradical initiators. A polarizing plate was manufactured in the same manner as in Example 1 except that the prepared photocurable adhesive was used instead of the water-based adhesive (the thickness of each adhesive layer was 2 μm to 3 μm).
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