Optical material containing phenanthroimidazole structure, and preparation method and application thereof
An optical material, phenanthroimidazole technology, applied in the direction of luminescent materials, chemical instruments and methods, organic chemistry, etc., can solve the problem of low quantum efficiency of solid-state film aggregated fluorescence
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[0055] Following the above technical scheme, this embodiment provides an optical material containing a phenanthroimidazole structure, which is denoted as the target product 8, and the structural formula of the target product 8 is as follows:
[0056]
[0057] The preparation method of the target product 8 of the present embodiment comprises the following steps:
[0058] Step 1, dissolve 10mmoL of 4-bromobenzaldehyde, 10mmoL of 4-tert-butylaniline and 10mmoL of 9,10-phenanthrenequinone in acetic acid-ammonium acetate buffer solution, stir and mix at 120°C for 2h, and mix well Finally, the crude product of 4-bromophenanthroimidazole was obtained, and the crude product of 4-bromophenanthroimidazole was washed with methanol, separated by filtration, vacuum dried and purified by column chromatography to obtain the purified product of 4-bromophenanthroimidazole.
[0059] In step one of the present embodiment, the preparation process of acetic acid-ammonium acetate buffer solution...
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