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Optical material containing phenanthroimidazole structure, and preparation method and application thereof

An optical material, phenanthroimidazole technology, applied in the direction of luminescent materials, chemical instruments and methods, organic chemistry, etc., can solve the problem of low quantum efficiency of solid-state film aggregated fluorescence

Active Publication Date: 2021-09-10
王玮铖
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] In view of the defects and deficiencies in the prior art, the purpose of the present invention is to provide an optical material containing a phenanthroimidazole structure, a preparation method and an application thereof, so as to solve the low technology of the existing organic semiconductor optical material solid-state thin-film aggregation fluorescence quantum efficiency question

Method used

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  • Optical material containing phenanthroimidazole structure, and preparation method and application thereof
  • Optical material containing phenanthroimidazole structure, and preparation method and application thereof
  • Optical material containing phenanthroimidazole structure, and preparation method and application thereof

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Embodiment

[0055] Following the above technical scheme, this embodiment provides an optical material containing a phenanthroimidazole structure, which is denoted as the target product 8, and the structural formula of the target product 8 is as follows:

[0056]

[0057] The preparation method of the target product 8 of the present embodiment comprises the following steps:

[0058] Step 1, dissolve 10mmoL of 4-bromobenzaldehyde, 10mmoL of 4-tert-butylaniline and 10mmoL of 9,10-phenanthrenequinone in acetic acid-ammonium acetate buffer solution, stir and mix at 120°C for 2h, and mix well Finally, the crude product of 4-bromophenanthroimidazole was obtained, and the crude product of 4-bromophenanthroimidazole was washed with methanol, separated by filtration, vacuum dried and purified by column chromatography to obtain the purified product of 4-bromophenanthroimidazole.

[0059] In step one of the present embodiment, the preparation process of acetic acid-ammonium acetate buffer solution...

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Abstract

The invention provides an optical material containing a phenanthroimidazole structure, and a preparation method and application thereof. According to the optical material containing the phenanthroimidazole structure, the efficient fluorescence quantum efficiency characteristic of anthracene is used as a bridge, and by means of the electron-withdrawing carbazole group electron-donating property of phenanthroimidazole, carrier injection and transmission are more balanced, so that the device performance can be improved; and meanwhile, a large-steric-hindrance distortion structure is adopted, so that the fluorescence quantum efficiency of a solid film aggregation state is improved, and efficient blue light emission can be performed in an organic solvent. When the optical material containing the phenanthroimidazole structure is used as a light-emitting layer material for manufacturing an organic light-emitting semiconductor device, the light-emitting efficiency and the light-emitting brightness of the organic light-emitting semiconductor device can be improved, and the structural formula of the material is as shown in formula I in the specification.

Description

technical field [0001] The invention belongs to the technical field of photoelectric materials, and relates to an optical material containing a phenanthroimidazole structure, in particular to an optical material containing a phenanthroimidazole structure, a preparation method and an application. Background technique [0002] Road driving safety has always been the most important issue for vehicle owners and traffic management departments, but the hidden dangers caused by low-visibility driving environment (rain, snow, dense fog, haze and other low-visibility weather conditions) are obvious. When the vehicle is driving at night or in low-visibility weather conditions, when there are no light-spotting objects or reference objects on both sides of the road, the light is easy to astigrate, the light becomes dim, and the visibility becomes low. [0003] Due to the problem of the viewing angle or brightness of road signs, road guidance signs are difficult to identify or fail at ni...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07D403/10C09K11/06H01L51/54
CPCC07D403/10C09K11/06C09K2211/1011C09K2211/1029C09K2211/1044H10K85/626H10K85/615H10K85/6572
Inventor 王玮铖邢龙江
Owner 王玮铖
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