A plasma discharge device and method of decomposing hydrogen sulfide

A discharge device and plasma technology, applied in the field of ion chemistry, can solve the problems of high decomposition energy consumption and low hydrogen sulfide conversion rate, etc.

Pending Publication Date: 2020-07-07
CHINA PETROLEUM & CHEM CORP +1
View PDF8 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0009] The purpose of the present invention is to overcome the defects of low hydrogen sulfide conversion rate and high decomposition energy consumption in the low-temperature plasma reactor provided by the prior art when it is used for the decomposition of hydrogen sulfide, and provide a new method that can improve the conversion rate of hydrogen sulfide And a plasma reactor for reducing decomposition energy consumption and a method for decomposing hydrogen sulfide using the reactor

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • A plasma discharge device and method of decomposing hydrogen sulfide

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0104] use figure 1 The shown low-temperature plasma reactor performs hydrogen sulfide decomposition reaction, and the specific structure and structural parameters of the low-temperature plasma reactor are as follows:

[0105] The reactor includes:

[0106] A first cavity, the first cavity is respectively provided with a first inlet, a gas product outlet and a liquid product outlet, wherein the side wall of the first cavity is formed by an external electrode, and forms the outer electrode The material is stainless steel metal foil, and the external electrode is grounded;

[0107] The second cavity, the second cavity is nested inside the first cavity, and the second cavity is respectively provided with a second inlet and a second outlet, and the side walls of the second cavity are all Formed by internal electrodes, the material forming the internal electrodes is stainless steel, and the internal electrodes are connected to a high-voltage power supply;

[0108] The lower edge...

Embodiment 2

[0135] The present embodiment adopts the plasma reactor similar to embodiment 1 to carry out the decomposition reaction of hydrogen sulfide, the difference is, in the present embodiment:

[0136] The external electrode is arranged on the inner side wall of the first cavity, and the external electrode is connected to a high-voltage power supply, and the material forming the external electrode is stainless steel metal foil; and the side wall of the second cavity is grounded, so that the second cavity The sidewall serves as the ground electrode.

[0137] L 2 with the thickness of the barrier dielectric D 1 ratio of 1:1; and H 1 :L 3 =1:280.

[0138] In this embodiment, H is introduced into the first cavity of the low-temperature plasma reactor from the first inlet. 2 S / Ar mixed gas, where H 2 The volume fraction of S is 30%, and the flow rate of the mixed gas is controlled so that the average residence time of the gas in the discharge area is 11.1s. In this embodiment, the ...

Embodiment 3

[0142] The present embodiment adopts the plasma reactor similar to embodiment 1 to carry out the decomposition reaction of hydrogen sulfide, the difference is, in the present embodiment:

[0143] The outer electrode is arranged around the inner side wall of the first cavity, the material forming the outer electrode is stainless steel metal foil, the outer electrode is grounded, and the inner electrode is connected to a high-voltage power supply;

[0144] L 2 with the thickness of the barrier dielectric D 1 ratio of 15:1; and H 1 :L 3 =1:400.

[0145] All the other specific structures and structural parameters are the same as in Example 1.

[0146] In this embodiment, H is introduced into the first cavity of the low-temperature plasma reactor from the first inlet. 2 S / H 2 mixed gas, where H 2 The volume fraction of S is 90%, the flow rate of the mixed gas is controlled so that the average residence time of the gas in the discharge area is 16.4s, and the reaction pressure...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention relates to the field of plasma chemistry, and discloses a plasma discharge device and a method for decomposing hydrogen sulfide; the discharge device comprises a first cavity (1), a second cavity (2), an inner electrode (3), an outer electrode (4) and a blocking medium (6); the inner electrode (3) and the outer electrode (4) are both solid electrodes, and the shapes of the inner electrode (3) and the outer electrode (4) are matched with each other to form an equal-diameter structure. The plasma discharge device provided by the invention can realize continuous and stable operationof a hydrogen sulfide decomposition process under an obviously high hydrogen sulfide conversion rate, and the reactor can realize long-period operation.

Description

technical field [0001] The invention relates to the field of plasma chemistry, in particular to a plasma discharge device and a method for decomposing hydrogen sulfide. Background technique [0002] Hydrogen sulfide (H 2 S) is a highly toxic and foul-smelling acid gas, which not only causes corrosion of metals and other materials, but also endangers human health and pollutes the environment. At present, large and medium-sized refineries in my country adopt the traditional Claus method (Claus) to treat 2 S tail gas, and recover sulfur. The method recovers only the sulfur in hydrogen sulfide, but converts the valuable hydrogen into water. From the perspective of comprehensive utilization of resources, hydrogen resources have not been effectively utilized in the traditional hydrogen sulfide recovery process. [0003] Therefore, the decomposition of hydrogen sulfide into sulfur and hydrogen has gradually become a technical field that researchers at home and abroad pay close ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): C01B3/04C01B17/04
CPCC01B3/04C01B17/0495Y02E60/36
Inventor 任君朋张婧张树才张铁周明川孙峰徐伟石宁朱云峰
Owner CHINA PETROLEUM & CHEM CORP
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap