Lithium-ion battery electrolyte and lithium-ion battery
A lithium-ion battery, electrolyte technology, applied in the direction of electrolyte, secondary battery, secondary battery repair/maintenance, etc., can solve the problems of loss of electrical contact of negative electrode materials, battery capacity decay, powdering of negative electrode materials, etc., to improve high temperature Effect of cycling and high temperature storage performance
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Embodiment 1
[0047] Preparation of high nickel positive electrode silicon carbon negative electrode lithium ion battery electrolyte:
[0048] In a glove box (model Universal (1800 / 750 / 900)) with moisture < 1ppm, put ethylene carbonate, ethyl methyl carbonate, diethyl carbonate, propyl propionate in a volume ratio of 20:40:30:10 well mixed.
[0049] Then, 1.1 mol / L lithium hexafluorophosphate was added to the mixed solvent, and stirred to completely dissolve it.
[0050] Then add succinonitrile, vinylene carbonate, fluoroethylene carbonate, 1,3-propane sultone and lithium difluorophosphate, stir the system evenly, and obtain the high-nickel positive electrode silicon carbon negative electrode lithium ion battery electrolyte.
[0051] Wherein, the quality of succinonitrile accounts for 0.5% of the total mass of the electrolyte, the quality of vinylene carbonate accounts for 0.5% of the total mass of the electrolyte, and the quality of fluoroethylene carbonate accounts for 5% of the total ma...
Embodiment 2
[0059] Preparation of high nickel positive electrode silicon carbon negative electrode lithium ion battery electrolyte:
[0060] In a glove box (model Universal (1800 / 750 / 900)) with moisture <1ppm, ethylene carbonate, ethyl methyl carbonate, diethyl carbonate, propyl propionate in a volume ratio of 20:40:30:10 well mixed.
[0061] Then, 1.1 mol / L lithium hexafluorophosphate was added to the mixed solvent, and stirred to completely dissolve it.
[0062] Then add succinonitrile, vinylene carbonate, fluoroethylene carbonate, 1,3-propane sultone and lithium difluorophosphate, stir the system evenly, and obtain the high-nickel positive electrode silicon carbon negative electrode lithium ion battery electrolyte.
[0063] Wherein, the quality of succinonitrile is promoted to 1% of the total mass of the electrolyte, the quality of vinylene carbonate accounts for 0.5% of the total mass of the electrolyte, and the quality of fluoroethylene carbonate accounts for 5% of the total mass of...
Embodiment 3
[0071] Preparation of high nickel positive electrode silicon carbon negative electrode lithium ion battery electrolyte:
[0072] In a glove box (model Universal (1800 / 750 / 900)) with moisture < 1ppm, put ethylene carbonate, ethyl methyl carbonate, diethyl carbonate, propyl propionate in a volume ratio of 20:40:30:10 well mixed.
[0073] Then, 1.1 mol / L lithium hexafluorophosphate was added to the mixed solvent, and stirred to completely dissolve it.
[0074] Then add succinonitrile, vinylene carbonate, fluoroethylene carbonate, 1,3-propane sultone and lithium difluorophosphate, stir the system evenly, and obtain the high-nickel positive electrode silicon carbon negative electrode lithium ion battery electrolyte.
[0075] Wherein, the quality of succinonitrile accounts for 0.5% of the total mass of the electrolyte, the quality of vinylene carbonate accounts for 1% of the total mass of the electrolyte, and the quality of fluoroethylene carbonate accounts for 5% of the total mass...
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