Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Compound reducing agent and reduction dyeing method

A technology of reducing agent and dye, which is applied in the field of dyeing, can solve the problems of decreased tear strength, insufficiently stable fabrics, poor soaping fastness, etc., and achieve the effects of stable reduction potential value, improved production efficiency, and slow decomposition rate

Active Publication Date: 2019-11-15
李瑞卿 +2
View PDF6 Cites 10 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The above dyeing methods mostly have the following problems: (1) Polyester is dyed with disperse dyes, and the light fastness is poor; after dyeing, reduction cleaning is required, and the color fastness of deep and thick colors is poor, and fades and grays after washing; When dyeing dyes, most of them need to use high-temperature process, and the cost of energy consumption is relatively high; disperse dyes are also prone to heat condensation, which is easy to cause defects such as color flowers and stains; There is a problem that it cannot meet the needs of consumers; the level dyeing property of nylon dyed with reactive dyes is poor, and high-temperature dyeing can easily cause the fabric to feel hard and even reduce the tear strength, especially 10-30D light and thin nylon. The strength damage is relatively large; (3) When reactive dyes are dyed in dark colors, the soaping fastness of the dyed finished product is generally poor, and it is easy to fade, lighten, and become old after repeated washing; the fabrics dyed with reactive dyes are not resistant to rinsing, if 84 disinfectant is added to the laundry It will cause partial decolorization and affect the appearance of wearing; (4) the dyeing process of acid or reactive dyes is longer, and the operation control is more difficult
Leucoic acid is difficult to process and is relatively seldom used; suspension dyeing is more commonly used, but the dye suspension is insoluble in water, and the dye molecule particles in the dye solution are large, it is difficult to fully enter the fiber, and the binding force with the fiber is weak, so The optimum level of fastness that should be achieved cannot be guaranteed; the leuco dyeing method is to convert the vat dye into the sodium salt of the leuco by pre-reduction, which is absorbed by the fiber in the dye bath, and then oxidized to form a water-insoluble dye The color lake is fixed on the fiber, which can give full play to the advantages of vat dyes
[0005] However, the existing leuco dyeing method still has the following disadvantages: the initial dyeing is faster, and it is easy to dye flowers; the amount of caustic soda and reducing agent is still high, which is easy to cause fiber damage
Some factories add softeners and antistatic agents to solve the above problems, which brings difficulties in subsequent dyeing and finishing
[0009] The dyeing of vat dyes generally adopts the suspension pad dyeing method in the pad dyeing process, and the leuco dyeing method cannot be widely used in the pad dyeing process. The main reason is that the reducing agent decomposes too fast in the leuco state, is not stable enough and the fabric Easy to dye flowers

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Compound reducing agent and reduction dyeing method
  • Compound reducing agent and reduction dyeing method
  • Compound reducing agent and reduction dyeing method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] This embodiment is a comparative experiment of the composite reducing agent and hydrosulfite under the same alkaline environment.

[0036] The higher the concentration of mother liquor, the stronger its reducibility. Configure the high-concentration mother liquor of the composite reducing agent and hydrosulfite of the same concentration, configure the alkali of 40g / L, the mother liquor 1 of the composite reducing agent of the present invention of 50g / L, configure the mother liquor of 40g / L alkali, and the hydrosulfite of 50g / L 2.

[0037] Dilute the two mother liquors by 5 times and 10 times respectively, and measure and observe the reduction potential value changes of the mother liquor and the diluent. After the mother liquor is prepared, measure its reduction potential value. The reduction potential value of the mother liquor is measured 15 minutes after the mother liquor is diluted 5 times. The specific ingredients and measurement results are shown in Table 1.

[...

Embodiment 2

[0043] 20g / L, 25g / L, 30g / L, 40g / L, 50g / L composite reducing agents will be prepared respectively, and under different alkalinity, the preparation solution will be measured at room temperature after 1 hour and 20 hours. Reductive changes. See Table 2 for details.

[0044] Table 2 The measured value of the solution placed for 1 hour

[0045]

[0046] Table 3 Measured value after placing the solution for 20 hours

[0047]

[0048] According to the data, the composite reducing agent of the present invention is very stable in the high-concentration region, and the potential fluctuation is small. When the combined alkali concentration is above 30g / L and the composite reducing agent is above 20g / L, the leucosome sodium salt state can be stably formed. The composite reducing agent of the present invention with the same concentration is placed in the same alkaline environment, after being placed for 1 hour and after being placed for 20 hours, its reducing potential value does ...

Embodiment 3

[0050] In this embodiment, cotton loose fibers for color spinning are used, and the composite reducing agent of the present invention is used to carry out dyeing by exhaust dyeing process. The specific process is as follows:

[0051] Configure high-concentration leucochrome sodium salt dye solution, the specific steps are as follows: first add 50wt% water in the container, turn on the agitator, heat up to 30-60°C and pour in caustic soda; pour in the dye while heating up and stirring , fully stirred for 20-30min; add water to cool down to 50°C, add composite reducing agent, stir for 45min, add cold water to 100wt% liquid volume for later use. At this time, the leucosome sodium salt staining solution is in a microcolloid state. The specific ingredients are shown in Table 4 and Table 5:

[0052] Table 4 Composition list

[0053] 3GL yellow FB red caustic soda Compound reducing agent Concentration(g / L) 5 60 50 40

[0054] Table 5 The ratio of co...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention discloses a compound reducing agent with a stable chemical potential and not containing sodium hydrosulfite. The compound reducing agent is prepared from, by weight, 30-75% of thiourea dioxide, 60-20% of reducing sugar and 10-5% of one of sodium nitrite, acrylamide, furfural, cyclohexanone and trichloroacetic acid in a chemical potential control agent. By using the compound reducingagent, the dyeing process combining the pretreatment with the dyeing procedure is achieved, the treatment time is reduced, the production efficiency is improved, the dyed finished product is dyed uniformly, and the strength and hand feeling are improved.

Description

technical field [0001] The invention relates to the field of dyeing, in particular to a composite reducing agent and a vat dyeing method. Background technique [0002] Dyeing methods are generally divided into disperse dyeing, acid dyeing, reactive dyeing and other dyeing methods according to different dyes. The above dyeing methods mostly have the following problems: (1) Polyester is dyed with disperse dyes, and the light fastness is poor; after dyeing, reduction cleaning is required, and the color fastness of deep and thick colors is poor, and fades and grays after washing; When dyeing dyes, most of them need to use high-temperature process, and the cost of energy consumption is relatively high; disperse dyes are also prone to heat condensation, which is easy to cause defects such as color flowers and stains; There is a problem that it cannot meet the needs of consumers; the level dyeing property of nylon dyed with reactive dyes is poor, and high-temperature dyeing can ea...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): D06P1/22
CPCD06P1/22D06P1/221
Inventor 李瑞卿王伟周长文
Owner 李瑞卿
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products